{
  "abstract": "The bulk and surface charge-driven interfacial structuring of two 1-decyl-3-methylimidazolium (C10C1Im) orthoborate ionic liquids (ILs), dispersed at various concentrations in the polar aprotic solvent propylene carbonate (PC), were studied using small angle neutron scattering (SANS) and neutron reflectivity (NR). In the bulk, the larger bis(mandelato)borate anion reduced the self-assembly capabilities of the blend relative to bis(oxalate)borate. At a charged Au electrode interface, a distinct interfacial region was detected in all the IL mixtures studied, which was attributed to two interdigitated bilayers of the cation, containing intercalated anions and solvent, and with bulk IL concentration dependence. Under applied potential, higher concentrations showed clear anion effects on the electro-structuring, whereas dilute solutions were anion independent. The complex bulk and electro-responsive interfacial structuring of such self-assembling IL systems in polar media are pertinent to the application of ILs as designer electrolytes for advanced electrochemical technologies, including next-generation batteries and control over the electrical double layer in capacitors.",
  "abstract_shown": true,
  "affiliations": [
    "Division of Surface and Corrosion Science, School of Engineering Sciences in Chemistry, Biotechnology and Health, KTH Royal Institute of Technology, SE-100 44Stockholm, Sweden.",
    "European Spallation Source, Data Management & Scientific Computing, Asmussens Allé 305, Kongens Lyngby, 2800Hovedstaden, Denmark.",
    "Department of Materials and Environmental Chemistry, Stockholm University, StockholmSE-114 18, Sweden.",
    "Department of Biological and Chemical Engineering, Aarhus University, AarhusN 8200, Denmark.",
    "School of Chemistry, University of New South Wales, Sydney, NSW2052, Australia.",
    "Wallenberg Initiative Materials Science for Sustainability, Division of Surface and Corrosion Science, KTH Royal Institute of Technology, SE-100 44Stockholm, Sweden.",
    "Australian Nuclear Science and Technology Organisation (ANSTO), Lucas Heights, Sydney, NSW2234, Australia.",
    "ISIS Pulsed Neutron and Muon Facility, Rutherford Appleton Laboratory, Didcot, OxfordshireOX11 0QX, U.K.",
    "System and Component Design, Department of Engineering Design, KTH Royal Institute of Technology, SE-100 44Stockholm, Sweden.",
    "Chemistry of Interfaces, Luleå University of Technology, Universitetsområdet, Luleå97187, Norrbotten, Sweden.",
    "Department of Electromechanical, Systems and Metal Engineering, Ghent University, B-9052Ghent, Belgium.",
    "Department of Physics, Umeå University, 907 36Umeå, Sweden.",
    "Surfaces, Processes and Formulation, RISE Research Institutes of Sweden, SE-100 44Stockholm, Sweden.",
    "Laboratoire de Tribologie et Dynamique Des Systèmes, École Centrale de Lyon, Écully, Lyon69134, Auvergne-Rhône-Alpes, France."
  ],
  "article_type": "research article",
  "arxiv": null,
  "author_total": 14,
  "authors": [
    {
      "affs": [
        0
      ],
      "name": "Georgia A Pilkington"
    },
    {
      "affs": [
        0,
        1,
        2,
        3,
        4
      ],
      "name": "Oliver S Hammond",
      "orcid": "0000-0002-5612-9343"
    },
    {
      "affs": [
        0
      ],
      "name": "Erik Bergendal"
    },
    {
      "affs": [
        0
      ],
      "name": "Anna Oleshkevych"
    },
    {
      "affs": [
        0,
        5
      ],
      "name": "Stuart J Brown",
      "orcid": "0000-0002-3324-2829"
    },
    {
      "affs": [
        0
      ],
      "name": "Sichao Li"
    },
    {
      "affs": [
        6
      ],
      "name": "Andrew Nelson",
      "orcid": "0000-0002-4548-3558"
    },
    {
      "affs": [
        6
      ],
      "name": "Liliana de Campo"
    },
    {
      "affs": [
        7
      ],
      "name": "Rebecca Welbourn",
      "orcid": "0000-0002-4254-5354"
    },
    {
      "affs": [
        8
      ],
      "name": "Akepati Bhaskar Reddy",
      "orcid": "0000-0002-2716-8810"
    },
    {
      "affs": [
        2,
        9
      ],
      "name": "Manishkumar R Shimpi"
    },
    {
      "affs": [
        4,
        8,
        10
      ],
      "name": "Sergei Glavatskih",
      "orcid": "0000-0002-8738-0047"
    },
    {
      "affs": [
        2,
        3,
        11
      ],
      "name": "Anja-Verena Mudring",
      "orcid": "0000-0002-2800-1684"
    },
    {
      "affs": [
        0,
        4,
        5,
        12,
        13
      ],
      "name": "Mark W Rutland",
      "orcid": "0000-0002-8935-8070"
    }
  ],
  "bibtex": "https://research.draconitic.com/paper/01dsrmzr4008s.bib",
  "cited_by": 0,
  "doi": "10.1021/acs.langmuir.6c03265",
  "fulltext_url": "https://europepmc.org/articles/PMC13629669",
  "id": "01dsrmzr4008s",
  "issns": [
    "0743-7463",
    "1520-5827"
  ],
  "landing_url": "https://europepmc.org/article/MED/42916807",
  "language": "eng",
  "licence": "CC-BY",
  "licence_label": "CC BY",
  "licence_source": "article",
  "licence_url": "https://creativecommons.org/licenses/by/4.0/",
  "metadata_licence": null,
  "native_subjects": [
    [
      "openalex",
      "1503|Ionic liquids properties and applications"
    ]
  ],
  "openalex": "W7213437659",
  "pdf_url": "https://europepmc.org/articles/PMC13629669?pdf=render",
  "pmcid": "PMC13629669",
  "pmid": "42916807",
  "published": "2026-09-01",
  "publisher": null,
  "ris": "https://research.draconitic.com/paper/01dsrmzr4008s.ris",
  "sources": [
    {
      "first_seen": "2026-10-30T12:21:02Z",
      "native_id": "MED:42916807",
      "source": "europepmc",
      "url": "https://europepmc.org/article/MED/42916807"
    }
  ],
  "subjects": [
    {
      "field": "chemistry",
      "origin": "openalex:1503|Ionic liquids properties and applications",
      "subfield": "catalysis"
    }
  ],
  "title": "Self-Assembly Versus Surface Charge: Interfacial Response of Ionic Liquids.",
  "title_text": "Self-Assembly Versus Surface Charge: Interfacial Response of Ionic Liquids.",
  "type": "peer-reviewed",
  "updated_at": "2026-10-30T12:21:02Z",
  "url": "https://research.draconitic.com/paper/01dsrmzr4008s",
  "venue": "Langmuir : the ACS journal of surfaces and colloids",
  "versions": []
}