{
  "abstract": "oxidation of a series of substrates in order to ascertain the role and the importance of the ligand steric hindrance on the action of the catalytic core 1, previously shown to be an efficient catalyst for aliphatic and aromatic C-H bond oxidation. The study reveals a modest dependence of the output of the oxidation reactions on the presence of bulky substituents in the backbone of the catalyst, both in terms of activity and selectivity. This result supports a previously hypothesized catalytic mechanism, which is based on the hemi-lability of the metal complex. In the active form of the catalyst, one of the pyridine arms temporarily leaves the iron centre, freeing up a lot of room for the access of the substrate.",
  "abstract_shown": true,
  "affiliations": [],
  "article_type": null,
  "arxiv": null,
  "author_total": 9,
  "authors": [
    {
      "name": "Federico Frateloreto"
    },
    {
      "name": "Giorgio Capocasa"
    },
    {
      "name": "Giorgio Olivo"
    },
    {
      "name": "Karim Abdel Hady"
    },
    {
      "name": "Carla Sappino"
    },
    {
      "name": "Marika Di Berto Mancini"
    },
    {
      "name": "Stefano Levi Mortera"
    },
    {
      "name": "Osvaldo Lanzalunga"
    },
    {
      "name": "Stefano Di Stefano"
    }
  ],
  "bibtex": "https://research.draconitic.com/paper/042v0bqr98b1w.bib",
  "cited_by": 9,
  "doi": "10.1039/d0ra09677f",
  "fulltext_url": null,
  "id": "042v0bqr98b1w",
  "issns": [
    "2046-2069"
  ],
  "landing_url": "https://hal.science/hal-05786827v1",
  "language": "en",
  "licence": "CC-BY",
  "licence_label": "CC BY",
  "licence_source": "journal",
  "licence_url": "https://creativecommons.org/licenses/by/4.0/",
  "metadata_licence": null,
  "native_subjects": [
    [
      "hal",
      "0.chim"
    ],
    [
      "openalex",
      "1604|Metal-Catalyzed Oxygenation Mechanisms"
    ]
  ],
  "openalex": "W3114587551",
  "pdf_url": "https://pubs.rsc.org/en/content/articlepdf/2021/ra/d0ra09677f",
  "pmcid": null,
  "pmid": null,
  "published": "2026-10-08",
  "publisher": "Royal Society of Chemistry",
  "ris": "https://research.draconitic.com/paper/042v0bqr98b1w.ris",
  "sources": [
    {
      "first_seen": "2026-10-30T12:17:51Z",
      "native_id": "hal-05786827",
      "source": "hal",
      "url": "https://hal.science/hal-05786827v1"
    }
  ],
  "subjects": [
    {
      "field": "chemistry",
      "origin": "openalex:1604|Metal-Catalyzed Oxygenation Mechanisms",
      "subfield": "inorganic"
    }
  ],
  "title": "Increasing the steric hindrance around the catalytic core of a self-assembled imine-based non-heme iron catalyst for C–H oxidation",
  "title_text": "Increasing the steric hindrance around the catalytic core of a self-assembled imine-based non-heme iron catalyst for C–H oxidation",
  "type": "peer-reviewed",
  "updated_at": "2026-10-30T12:17:51Z",
  "url": "https://research.draconitic.com/paper/042v0bqr98b1w",
  "venue": "RSC Advances",
  "versions": []
}