{
  "abstract": "Palladium(II) or platinum(II) are often incorporated into metallo-supramolecular architectures as their square-planar geometry and relative accessibility make them attractive targets. The square-planar cationic panels where palladium(II) or platinum(II) are bound within these species frequently participate in interactions which enable host-guest chemistry or controlled conformation. We here investigate whether there could be a difference between the strength of interactions established by Pd(II) or Pt(II)-containing species. Analogous Pd(II) and Pt(II) model complexes were synthesized, and their behavior compared against aromatic and platinate guests. Predominantly through ¹H NMR techniques, we have established that Pt(II) can allow for π interactions with an aromatic guest roughly twice the strength of their Pd(II) counterparts, where binding is strong. Similarly, the interactions between the Pt(II) model complex with a platinate guest, were stronger than those of the Pd(II) model complex, although notably weak in both cases.",
  "abstract_shown": true,
  "affiliations": [
    "Research School of Chemistry, Australian National University, Canberra, Australia."
  ],
  "article_type": "research article",
  "arxiv": null,
  "author_total": 3,
  "authors": [
    {
      "affs": [
        0
      ],
      "name": "Jess L Algar",
      "orcid": "0000-0002-7460-0506"
    },
    {
      "affs": [
        0
      ],
      "name": "Rosemary J Goodwin",
      "orcid": "0000-0001-7821-5499"
    },
    {
      "affs": [
        0
      ],
      "name": "Dan Preston",
      "orcid": "0000-0002-1093-8153"
    }
  ],
  "bibtex": "https://research.draconitic.com/paper/097z1r4qb3jz2.bib",
  "cited_by": 0,
  "doi": "10.1002/asia.71018",
  "fulltext_url": "https://europepmc.org/articles/PMC13677020",
  "id": "097z1r4qb3jz2",
  "issns": [
    "1861-4728",
    "1861-471X"
  ],
  "landing_url": "https://europepmc.org/article/MED/42893478",
  "language": "eng",
  "licence": "CC-BY",
  "licence_label": "CC BY",
  "licence_source": "article",
  "licence_url": "https://creativecommons.org/licenses/by/4.0/",
  "metadata_licence": null,
  "native_subjects": [
    [
      "openalex",
      "1605|Supramolecular Chemistry and Complexes"
    ]
  ],
  "openalex": "W7222872719",
  "pdf_url": "https://europepmc.org/articles/PMC13677020?pdf=render",
  "pmcid": "PMC13677020",
  "pmid": "42893478",
  "published": "2026-10-01",
  "publisher": null,
  "ris": "https://research.draconitic.com/paper/097z1r4qb3jz2.ris",
  "sources": [
    {
      "first_seen": "2026-10-30T12:19:00Z",
      "native_id": "MED:42893478",
      "source": "europepmc",
      "url": "https://europepmc.org/article/MED/42893478"
    }
  ],
  "subjects": [
    {
      "field": "chemistry",
      "origin": "openalex:1605|Supramolecular Chemistry and Complexes",
      "subfield": "organic"
    }
  ],
  "title": "Relative Influence of Pd(II) and Pt(II) Metal Centers on the Strength of Interactions Between Planar Species.",
  "title_text": "Relative Influence of Pd(II) and Pt(II) Metal Centers on the Strength of Interactions Between Planar Species.",
  "type": "peer-reviewed",
  "updated_at": "2026-10-30T12:19:00Z",
  "url": "https://research.draconitic.com/paper/097z1r4qb3jz2",
  "venue": "Chemistry, an Asian journal",
  "versions": []
}