{
  "abstract": "The title salt, [Cu(C2H3O2)(C12H12N2O2)2](C15H6N7O10)·H2O, comprises a [Cu(MeObpy)2(C2H3O2)]+ complex cation (where MeObpy = 4,4'-dimeth-oxy-2,2'-bi-pyridine), a non-coordinating pnpz- anion (pnpz- = 3,5-bis-(2,4-di-nitro-phen-yl)-4-nitro-pyrazolate) and one inter-stitial water solvent mol-ecule. The central CuII atom is five-coordinate, with a coordination environment inter-mediate between square-pyramidal and trigonal-bipyramidal, defined by two chelating 4,4'-dimeth-oxy-2,2'-bi-pyridine ligands and one O atom of a monodentate acetate anion at 1.969 (3) Å. Two Cu-N bond lengths, 1.985 (3) and 2.006 (3) Å, are similar and shorter than the other two Cu-N bond lengths of 2.061 (3) and 2.148 (4) Å. In the crystal, the electron density from a region of disordered solvent mol-ecules (aceto-nitrile and water) was treated with the SQUEEZE routine in PLATON [Spek (2015 ▸). Acta Cryst. C71, 9-18]. Their contribution was not taken into account during refinement.",
  "abstract_shown": true,
  "affiliations": [
    "Department of Chemistry and Biochemistry Florida International University, Miami, FL 33199 USA."
  ],
  "article_type": "research article",
  "arxiv": null,
  "author_total": 3,
  "authors": [
    {
      "affs": [
        0
      ],
      "name": "Sherin Anto"
    },
    {
      "affs": [
        0
      ],
      "name": "Indranil Chakraborty",
      "orcid": "0000-0003-2842-211X"
    },
    {
      "affs": [
        0
      ],
      "name": "Raphael G Raptis",
      "orcid": "0000-0002-9522-0369"
    }
  ],
  "bibtex": "https://research.draconitic.com/paper/0cbpsxprx7msx.bib",
  "cited_by": 0,
  "doi": "10.1107/s2414314626010552",
  "fulltext_url": "https://europepmc.org/articles/PMC13741259",
  "id": "0cbpsxprx7msx",
  "issns": [
    "2414-3146"
  ],
  "landing_url": "https://europepmc.org/article/MED/42997372",
  "language": "eng",
  "licence": "CC-BY",
  "licence_label": "CC BY",
  "licence_source": "article",
  "licence_url": "https://creativecommons.org/licenses/by/4.0/",
  "metadata_licence": null,
  "native_subjects": [
    [
      "openalex",
      "1604|Crystal structures of chemical compounds"
    ]
  ],
  "openalex": "W7223008605",
  "pdf_url": "https://europepmc.org/articles/PMC13741259?pdf=render",
  "pmcid": "PMC13741259",
  "pmid": "42997372",
  "published": "2026-09-01",
  "publisher": null,
  "ris": "https://research.draconitic.com/paper/0cbpsxprx7msx.ris",
  "sources": [
    {
      "first_seen": "2026-11-09T15:20:42Z",
      "native_id": "MED:42997372",
      "source": "europepmc",
      "url": "https://europepmc.org/article/MED/42997372"
    }
  ],
  "subjects": [
    {
      "field": "chemistry",
      "origin": "openalex:1604|Crystal structures of chemical compounds",
      "subfield": "inorganic"
    }
  ],
  "title": "(Acetato-κO)bis-(4,4'-dimeth-oxy-2,2'-bi-pyridine-κ²N,N')copper(II) 3,5-bis-(2,4-di-nitro-phen-yl)-4-nitro-pyrazolate monohydrate.",
  "title_text": "(Acetato-κO)bis-(4,4'-dimeth-oxy-2,2'-bi-pyridine-κ²N,N')copper(II) 3,5-bis-(2,4-di-nitro-phen-yl)-4-nitro-pyrazolate monohydrate.",
  "type": "peer-reviewed",
  "updated_at": "2026-11-09T15:20:42Z",
  "url": "https://research.draconitic.com/paper/0cbpsxprx7msx",
  "venue": "IUCrData",
  "versions": []
}