{
  "abstract": "Circularly Polarized Luminescence (CPL) is extensively used in advanced photonics, optoelectronic technologies, and biomedicine. Considerable efforts have been made to maximize the dissymmetry factor (glum) and the brightness of CPL-emitting materials, particularly in the UV–vis range, but only very few materials emit efficient CPL in the red-NIR window. In this work, we present a simple method to generate a hybrid organic-inorganic material that delivers CPL in the red-NIR, with large glum and a Figure of Merit of 0.19 and 7.07 10−2, respectively. These hybrids are obtained by mixing a red-NIR phosphorescent achiral octahedral molybdenum cluster compound with a chiral bent-core liquid crystal that can self-assemble into helical nanofilaments upon cooling from 108°C. Photophysical studies show that the emission of the inorganic nanoemitter is not affected by the organic matrix while studies on the liquid crystal properties demonstrate that the self-organization of the host is only altered at cluster concentration higher than 5 wt.% which in turn leads to a decrease of the glum value.",
  "abstract_shown": true,
  "affiliations": [],
  "article_type": null,
  "arxiv": null,
  "author_total": 7,
  "authors": [
    {
      "name": "Jeanne Rebours"
    },
    {
      "name": "Shamima Akhter"
    },
    {
      "name": "Md Kamrul Hasan"
    },
    {
      "name": "Serge Paofai"
    },
    {
      "name": "Maria Amela-Cortes"
    },
    {
      "name": "Marianne Estelle Prévôt"
    },
    {
      "name": "Yann Molard"
    }
  ],
  "bibtex": "https://research.draconitic.com/paper/0vjfv8ap02nt0.bib",
  "cited_by": 0,
  "doi": "10.1002/adom.71409",
  "fulltext_url": null,
  "id": "0vjfv8ap02nt0",
  "issns": [
    "2195-1071"
  ],
  "landing_url": "https://hal.science/hal-05681950v1",
  "language": "en",
  "licence": "CC-BY-NC-ND-4.0",
  "licence_label": "CC BY-NC-ND 4.0",
  "licence_source": "article",
  "licence_url": "https://creativecommons.org/licenses/by-nc-nd/4.0/",
  "metadata_licence": null,
  "native_subjects": [
    [
      "hal",
      "0.chim"
    ],
    [
      "hal",
      "1.chim.mate"
    ],
    [
      "openalex",
      "2505|Luminescence and Fluorescent Materials"
    ]
  ],
  "openalex": "W7166589473",
  "pdf_url": "https://hal.science/hal-05681950/document",
  "pmcid": null,
  "pmid": null,
  "published": "2026-10-16",
  "publisher": "Wiley",
  "ris": "https://research.draconitic.com/paper/0vjfv8ap02nt0.ris",
  "sources": [
    {
      "first_seen": "2026-10-30T12:17:58Z",
      "native_id": "hal-05681950",
      "source": "hal",
      "url": "https://hal.science/hal-05681950v1"
    }
  ],
  "subjects": [
    {
      "field": "chemistry",
      "origin": "hal:1.chim.mate",
      "subfield": "materials-polymers"
    }
  ],
  "title": "Circularly Polarized Red-NIR Emission With High Dissymmetry Factor From Achiral [Mo6I8(OCOC2F5)6]2− Cluster Anion Embedded in a Bent-Core Liquid Crystal Host",
  "title_text": "Circularly Polarized Red-NIR Emission With High Dissymmetry Factor From Achiral [Mo6I8(OCOC2F5)6]2− Cluster Anion Embedded in a Bent-Core Liquid Crystal Host",
  "type": "peer-reviewed",
  "updated_at": "2026-10-30T12:17:58Z",
  "url": "https://research.draconitic.com/paper/0vjfv8ap02nt0",
  "venue": "Advanced Optical Materials",
  "versions": []
}