{
  "abstract": "A reliable and operationally simple protocol for the regioselective and enantioselective carbonylative Heck-Matsuda arylation of protected allylic alcohols followed by interception of the acyl–palladium intermediate with alcohols and organostannane in a Stille-type coupling was developed. This intermolecular carbonylative Heck method provides access to highly functionalized esters and methyl ketones with the formation of multiple carbon–carbon bonds and the construction of an all-carbon quaternary stereogenic center in a single step from readily available starting materials in good to excellent yields. The reaction displays a broad substrate scope, affording products that offer opportunities for further derivatization, including their conversion into enantioenriched functionalized furans.",
  "abstract_shown": true,
  "affiliations": [
    "Institute of Chemistry",
    "State University of Campinas",
    "Fluminense Federal University",
    "Institute of Science & Technology, Federal University of São Paulo, CEP 12231-280, São José dos Campos, SP, Brazil"
  ],
  "article_type": null,
  "arxiv": null,
  "author_total": 5,
  "authors": [
    {
      "affs": [
        0,
        1
      ],
      "name": "Sergei Aleksandrovich Gorbatov"
    },
    {
      "affs": [
        0,
        1
      ],
      "name": "Arnaldo Gomes de Oliveira Junior"
    },
    {
      "affs": [
        0,
        2
      ],
      "name": "Andrea Nastri de Luca Batista"
    },
    {
      "affs": [
        3
      ],
      "name": "João Marcos Batista Junior"
    },
    {
      "affs": [
        0,
        1
      ],
      "name": "Carlos Roque Duarte Correia"
    }
  ],
  "bibtex": "https://research.draconitic.com/paper/1c5ag8t9dxma5.bib",
  "cited_by": 0,
  "doi": "10.26434/chemrxiv.15008033/v1",
  "fulltext_url": null,
  "id": "1c5ag8t9dxma5",
  "issns": [],
  "landing_url": "https://chemrxiv.org/doi/full/10.26434/chemrxiv.15008033/v1",
  "language": null,
  "licence": "CC-BY-NC-ND",
  "licence_label": "CC BY-NC-ND",
  "licence_source": "journal",
  "licence_url": "https://creativecommons.org/licenses/by-nc-nd/4.0/",
  "metadata_licence": null,
  "native_subjects": [
    [
      "openalex",
      "1605|Catalytic Cross-Coupling Reactions"
    ]
  ],
  "openalex": "W7204758511",
  "pdf_url": "https://chemrxiv.org/doi/pdf/10.26434/chemrxiv.15008033/v1",
  "pmcid": null,
  "pmid": null,
  "published": "2026-08-30",
  "publisher": "American Chemical Society (ACS)",
  "ris": "https://research.draconitic.com/paper/1c5ag8t9dxma5.ris",
  "sources": [
    {
      "first_seen": "2026-10-30T12:17:17Z",
      "native_id": "10.26434/chemrxiv.15008033",
      "source": "chemrxiv",
      "url": "https://chemrxiv.org/doi/full/10.26434/chemrxiv.15008033/v1"
    }
  ],
  "subjects": [
    {
      "field": "chemistry",
      "origin": "openalex:1605|Catalytic Cross-Coupling Reactions",
      "subfield": "organic"
    }
  ],
  "title": "Regio and Stereoselective Multicomponent Palladium-Catalyzed Carbonylative Heck-Stille arylation of allylic alcohols derivatives",
  "title_text": "Regio and Stereoselective Multicomponent Palladium-Catalyzed Carbonylative Heck-Stille arylation of allylic alcohols derivatives",
  "type": "preprint",
  "updated_at": "2026-10-30T12:17:17Z",
  "url": "https://research.draconitic.com/paper/1c5ag8t9dxma5",
  "venue": "ChemRxiv",
  "versions": []
}