{
  "abstract": "Rh-catalyzed cascade C-H functionalization/annulation of ketimine-directed arenes with vinylcyclopropanes has been accomplished to access N-bridged cyclic frameworks. The procedure can be extended to vinylaziridine, vinyloxirane, and vinyl ethylene carbonate to furnish spirotetrahydroisoquinoline and spiroindane scaffolds. The versatile reactivity of the vinyl strained rings, functional group tolerance, and photophysical/molecular docking studies of the representative examples are the important practical features.",
  "abstract_shown": true,
  "affiliations": [
    "Department of Chemistry, Indian Institute of Technology Guwahati, Guwahati-781039, India.",
    "Department of Translational Medicine, All India Institute of Medical Sciences, Bhopal-462020, India."
  ],
  "article_type": "research article",
  "arxiv": null,
  "author_total": 4,
  "authors": [
    {
      "affs": [
        0
      ],
      "name": "Swati Samantaray"
    },
    {
      "affs": [
        0
      ],
      "name": "Sajal Roy",
      "orcid": "0009-0007-2848-9636"
    },
    {
      "affs": [
        1
      ],
      "name": "Mahesh Samantaray"
    },
    {
      "affs": [
        0
      ],
      "name": "Tharmalingam Punniyamurthy",
      "orcid": "0000-0003-4696-8896"
    }
  ],
  "bibtex": "https://research.draconitic.com/paper/1h2be20apqaaj.bib",
  "cited_by": 0,
  "doi": "10.1021/acs.orglett.6c03868",
  "fulltext_url": "https://europepmc.org/articles/PMC13682214",
  "id": "1h2be20apqaaj",
  "issns": [
    "1523-7060",
    "1523-7052"
  ],
  "landing_url": "https://europepmc.org/article/MED/42917741",
  "language": "eng",
  "licence": "CC-BY-NC-ND",
  "licence_label": "CC BY-NC-ND",
  "licence_source": "article",
  "licence_url": "https://creativecommons.org/licenses/by-nc-nd/4.0/",
  "metadata_licence": null,
  "native_subjects": [
    [
      "openalex",
      "1605|Catalytic C–H Functionalization Methods"
    ]
  ],
  "openalex": "W7220835534",
  "pdf_url": "https://europepmc.org/articles/PMC13682214?pdf=render",
  "pmcid": "PMC13682214",
  "pmid": "42917741",
  "published": "2026-10-01",
  "publisher": null,
  "ris": "https://research.draconitic.com/paper/1h2be20apqaaj.ris",
  "sources": [
    {
      "first_seen": "2026-10-30T12:20:36Z",
      "native_id": "MED:42917741",
      "source": "europepmc",
      "url": "https://europepmc.org/article/MED/42917741"
    }
  ],
  "subjects": [
    {
      "field": "chemistry",
      "origin": "openalex:1605|Catalytic C–H Functionalization Methods",
      "subfield": "organic"
    }
  ],
  "title": "Rh-Catalyzed Cascade C-H Functionalization/Annulation of Ketimine Directed Arenes with Vinylcyclopropanes: Access to Bridged Azaheterocycles.",
  "title_text": "Rh-Catalyzed Cascade C-H Functionalization/Annulation of Ketimine Directed Arenes with Vinylcyclopropanes: Access to Bridged Azaheterocycles.",
  "type": "peer-reviewed",
  "updated_at": "2026-10-30T12:20:36Z",
  "url": "https://research.draconitic.com/paper/1h2be20apqaaj",
  "venue": "Organic letters",
  "versions": []
}