{
  "abstract": "Deep eutectic solvents (DESs) have attracted considerable attention as sustainable, next-generation solvents. In this study, we report the formation of supramolecular eutectogels using mangiferin (MF), a naturally occurring C -glucosyl xanthone. MF successfully induced gelation in typical DESs composed of choline chloride and various hydrogen-bond donors, including urea, ethylene glycol, and glycerol. The gelation behavior was dependent on the hydrogen-bond donor, with significant differences observed in the time required for gelation. Furthermore, microscopic observations and XRD measurements revealed that MF formed distinct self-assembled network structures depending on the DES composition. Rheological measurements revealed the viscoelastic properties of the eutectogels, which supported the formation of three-dimensional supramolecular networks. These findings highlight the potential of MF as a bio-based gelator for DES-based soft materials and provide valuable insights into the rational design of sustainable supramolecular eutectogels for future applications.",
  "abstract_shown": true,
  "affiliations": [
    "United Graduate School of Drug Discovery and Medical Information Sciences, Gifu University, 1-1 Yanagido, Gifu, Japan, 501-1193",
    "Institute for Advanced Study, Gifu University, 1-1 Yanagido, Gifu, Japan, 501-1193",
    "Center for One Medicine Innovative Translational Research (COMIT), Institute for Advanced Study, Gifu University, 1-1 Yanagido, Gifu, Japan, 501-1193",
    "Department of Life Science and Chemistry, Graduate School of Natural Science and Technology, Gifu University, 1-1 Yanagido, Gifu, Japan, 501-1193",
    "Institute for Glyco-core Research (iGCORE), Gifu University, 1-1 Yanagido, Gifu, Japan, 501-1193",
    "Innovation Research Center for Quantum Medicine, Graduate School of Medicine, Gifu University, 1-1 Yanagido, Gifu, Japan, 501-1193"
  ],
  "article_type": null,
  "arxiv": null,
  "author_total": 4,
  "authors": [
    {
      "affs": [
        0
      ],
      "name": "Fumiko Nakagawa"
    },
    {
      "affs": [
        0,
        1,
        2
      ],
      "name": "Sayuri L. Higashi",
      "orcid": "0000-0001-8488-4808"
    },
    {
      "affs": [
        3
      ],
      "name": "Shin-ichiro Kawano",
      "orcid": "0000-0001-9109-3115"
    },
    {
      "affs": [
        0,
        2,
        3,
        4,
        5
      ],
      "name": "Masato Ikeda",
      "orcid": "0000-0003-4097-8292"
    }
  ],
  "bibtex": "https://research.draconitic.com/paper/1m7c2v6rn5fme.bib",
  "cited_by": 0,
  "doi": "10.26434/chemrxiv.15010534/v1",
  "fulltext_url": null,
  "id": "1m7c2v6rn5fme",
  "issns": [],
  "landing_url": "https://chemrxiv.org/doi/full/10.26434/chemrxiv.15010534/v1",
  "language": null,
  "licence": "CC-BY-NC-ND",
  "licence_label": "CC BY-NC-ND",
  "licence_source": "journal",
  "licence_url": "https://creativecommons.org/licenses/by-nc-nd/4.0/",
  "metadata_licence": null,
  "native_subjects": [
    [
      "openalex",
      "2502|Supramolecular Self-Assembly in Materials"
    ]
  ],
  "openalex": "W7222112875",
  "pdf_url": "https://chemrxiv.org/doi/pdf/10.26434/chemrxiv.15010534/v1",
  "pmcid": null,
  "pmid": null,
  "published": "2026-10-15",
  "publisher": "American Chemical Society (ACS)",
  "ris": "https://research.draconitic.com/paper/1m7c2v6rn5fme.ris",
  "sources": [
    {
      "first_seen": "2026-10-30T12:17:24Z",
      "native_id": "10.26434/chemrxiv.15010534",
      "source": "chemrxiv",
      "url": "https://chemrxiv.org/doi/full/10.26434/chemrxiv.15010534/v1"
    }
  ],
  "subjects": [
    {
      "field": "chemistry",
      "origin": "openalex:2502|Supramolecular Self-Assembly in Materials",
      "subfield": "materials-polymers"
    }
  ],
  "title": "Supramolecular Eutectogels Based on Mangiferin, a Glucose-Appended Natural Herbal Compound",
  "title_text": "Supramolecular Eutectogels Based on Mangiferin, a Glucose-Appended Natural Herbal Compound",
  "type": "preprint",
  "updated_at": "2026-10-30T12:17:24Z",
  "url": "https://research.draconitic.com/paper/1m7c2v6rn5fme",
  "venue": "ChemRxiv",
  "versions": []
}