{
  "abstract": "Reactions of an Al(I) center with Sb–Cl, Bi–Cl and, notably, Sb–H reagents afford a family of Al(III) complexes featuring structurally characterized, pnictogen–halide and –hydride bonds. The Sb–H reaction is particularly striking, simultaneously forging Al–Sb and Al–H bonds to give the first hydridoaluminastibane establishing the previously unknown Al(Sb)(H) functional group. These results introduce pnictogen hydride oxidative addition as a new strategy for Al–Sb bond formation and expands the reactivity landscape of hydrostibination.",
  "abstract_shown": true,
  "affiliations": [
    "Department of Chemistry, Western University, 1151 Richmond Street, London, Canada, N8K 3G6",
    "Department of Chemistry, Dalhousie University, 6274 Coburg Road, Halifax, NS, B3H 4R2",
    "Department of Chemistry, University of Victoria, 3800 Finnerty Road, Victoria, BC, V8P 5C2"
  ],
  "article_type": null,
  "arxiv": null,
  "author_total": 6,
  "authors": [
    {
      "affs": [
        0
      ],
      "name": "Elizabeth A. McKenzie"
    },
    {
      "affs": [
        0
      ],
      "name": "Gabriel J. Jobin"
    },
    {
      "affs": [
        1
      ],
      "name": "Mitchell A. MacEachern"
    },
    {
      "affs": [
        0
      ],
      "name": "A. Dina Dilinaer"
    },
    {
      "affs": [
        1,
        2
      ],
      "name": "Saurabh S. Chitnis"
    },
    {
      "affs": [
        0
      ],
      "name": "Marcus W. Drover",
      "orcid": "0000-0002-2186-1040"
    }
  ],
  "bibtex": "https://research.draconitic.com/paper/1x6sgg3a1rhdr.bib",
  "cited_by": 0,
  "doi": "10.26434/chemrxiv.15008970/v1",
  "fulltext_url": null,
  "id": "1x6sgg3a1rhdr",
  "issns": [],
  "landing_url": "https://chemrxiv.org/doi/full/10.26434/chemrxiv.15008970/v1",
  "language": null,
  "licence": "CC-BY",
  "licence_label": "CC BY",
  "licence_source": "journal",
  "licence_url": "https://creativecommons.org/licenses/by/4.0/",
  "metadata_licence": null,
  "native_subjects": [
    [
      "openalex",
      "1604|Synthesis and characterization of novel inorganic/organometallic compounds"
    ]
  ],
  "openalex": "W7213443382",
  "pdf_url": "https://chemrxiv.org/doi/pdf/10.26434/chemrxiv.15008970/v1",
  "pmcid": null,
  "pmid": null,
  "published": "2026-09-17",
  "publisher": "American Chemical Society (ACS)",
  "ris": "https://research.draconitic.com/paper/1x6sgg3a1rhdr.ris",
  "sources": [
    {
      "first_seen": "2026-10-30T12:17:19Z",
      "native_id": "10.26434/chemrxiv.15008970",
      "source": "chemrxiv",
      "url": "https://chemrxiv.org/doi/full/10.26434/chemrxiv.15008970/v1"
    }
  ],
  "subjects": [
    {
      "field": "chemistry",
      "origin": "openalex:1604|Synthesis and characterization of novel inorganic/organometallic compounds",
      "subfield": "inorganic"
    }
  ],
  "title": "Hydridoaluminastibanes: A New Class of Al–Sb Bonded Main-Group Compound",
  "title_text": "Hydridoaluminastibanes: A New Class of Al–Sb Bonded Main-Group Compound",
  "type": "preprint",
  "updated_at": "2026-10-30T12:17:19Z",
  "url": "https://research.draconitic.com/paper/1x6sgg3a1rhdr",
  "venue": "ChemRxiv",
  "versions": []
}