{
  "abstract": "A nickel catalyst has been successfully explored for the carbonylative synthesis of 1,6-diketones from cycloalkylsilyl peroxides and arylboronic acids. Under nickel catalysis, using cycloalkylsilyl peroxides as carbonyl-containing alkyl radicals and formic acid as a safe CO source, the protocol affords a variety of 1,6-diketones in good yields, in general with promising functional group tolerance. This transformation represents a general and complementary strategy for the construction of valuable 1,6-diketones.",
  "abstract_shown": true,
  "affiliations": [
    "School of Chemistry and Chemical Engineering, Key Laboratory of Surface & Interface Science of Polymer Materials of Zhejiang Province, Zhejiang Sci-Tech University, Hangzhou, Zhejiang310018, People's Republic of China.",
    "Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, Liaoning116023, China.",
    "Leibniz-Institut für Katalyse e.V., Albert-Einstein-Straße 29a, 18059Rostock, Germany."
  ],
  "article_type": "research article",
  "arxiv": null,
  "author_total": 5,
  "authors": [
    {
      "affs": [
        0
      ],
      "name": "Jiacong Ma"
    },
    {
      "affs": [
        0
      ],
      "name": "Zilin Huang"
    },
    {
      "affs": [
        0
      ],
      "name": "Hongyi Huang"
    },
    {
      "affs": [
        0
      ],
      "name": "Xinxin Qi"
    },
    {
      "affs": [
        1,
        2
      ],
      "name": "Xiao-Feng Wu",
      "orcid": "0000-0001-6622-3328"
    }
  ],
  "bibtex": "https://research.draconitic.com/paper/35gvrhqfgacdj.bib",
  "cited_by": 0,
  "doi": "10.1021/acs.orglett.6c03636",
  "fulltext_url": "https://europepmc.org/articles/PMC13640422",
  "id": "35gvrhqfgacdj",
  "issns": [
    "1523-7060",
    "1523-7052"
  ],
  "landing_url": "https://europepmc.org/article/MED/42917806",
  "language": "eng",
  "licence": "CC-BY",
  "licence_label": "CC BY",
  "licence_source": "article",
  "licence_url": "https://creativecommons.org/licenses/by/4.0/",
  "metadata_licence": null,
  "native_subjects": [
    [
      "openalex",
      "1605|Catalytic Cross-Coupling Reactions"
    ]
  ],
  "openalex": "W7213923264",
  "pdf_url": "https://europepmc.org/articles/PMC13640422?pdf=render",
  "pmcid": "PMC13640422",
  "pmid": "42917806",
  "published": "2026-10-01",
  "publisher": null,
  "ris": "https://research.draconitic.com/paper/35gvrhqfgacdj.ris",
  "sources": [
    {
      "first_seen": "2026-10-30T12:20:36Z",
      "native_id": "MED:42917806",
      "source": "europepmc",
      "url": "https://europepmc.org/article/MED/42917806"
    }
  ],
  "subjects": [
    {
      "field": "chemistry",
      "origin": "openalex:1605|Catalytic Cross-Coupling Reactions",
      "subfield": "organic"
    }
  ],
  "title": "Nickel-Catalyzed Carbonylative Synthesis of 1,6-Diketones from Cycloalkylsilyl Peroxides and Arylboronic Acids.",
  "title_text": "Nickel-Catalyzed Carbonylative Synthesis of 1,6-Diketones from Cycloalkylsilyl Peroxides and Arylboronic Acids.",
  "type": "peer-reviewed",
  "updated_at": "2026-10-30T12:20:36Z",
  "url": "https://research.draconitic.com/paper/35gvrhqfgacdj",
  "venue": "Organic letters",
  "versions": []
}