{
  "abstract": "We describe herein a convenient strategy for the preparation of β‐C‐glycosides via the addition of radical species onto exoglycals. This method is efficient, general and achieved in mild conditions starting from xanthates derivatives and using triethylborane as initiator and 4‐tert‐butylcatechol as hydrogen atom source. This hydroalkylation reaction is completely regioselective with moderate to complete stereoselectivity.",
  "abstract_shown": true,
  "affiliations": [
    "Institut De Chimie et Biochimie Moléculaires Et Supramoléculaires Laboratoire De Chimie Organique 2—Glycochimie UMR‐CNRS 5246‐Université Claude Bernard Lyon 1 France",
    "Laboratoire Des Multimatériaux et Interfaces UMR‐CNRS 5615‐Université Claude Bernard Lyon 1 France"
  ],
  "article_type": "research article",
  "arxiv": null,
  "author_total": 3,
  "authors": [
    {
      "affs": [
        0
      ],
      "name": "Noémie Murard"
    },
    {
      "affs": [
        1
      ],
      "name": "Guillaume Pilet",
      "orcid": "0000-0002-0548-0651"
    },
    {
      "affs": [
        0
      ],
      "name": "David Gueyrard",
      "orcid": "0000-0002-9657-3836"
    }
  ],
  "bibtex": "https://research.draconitic.com/paper/3s6351j1y5z6w.bib",
  "cited_by": 0,
  "doi": "10.1002/chem.71515",
  "fulltext_url": "https://pmc.ncbi.nlm.nih.gov/articles/PMC13715995/",
  "id": "3s6351j1y5z6w",
  "issns": [
    "0947-6539",
    "1521-3765"
  ],
  "landing_url": "https://doi.org/10.1002/chem.71515",
  "language": "en",
  "licence": "CC-BY-NC-ND-4.0",
  "licence_label": "CC BY-NC-ND 4.0",
  "licence_source": "article",
  "licence_url": "https://creativecommons.org/licenses/by-nc-nd/4.0/",
  "metadata_licence": null,
  "native_subjects": [
    [
      "heading",
      "Research Article"
    ],
    [
      "openalex",
      "1605|Carbohydrate Chemistry and Synthesis"
    ]
  ],
  "openalex": "W7172313629",
  "pdf_url": null,
  "pmcid": "PMC13715995",
  "pmid": "42545823",
  "published": "2026-08-03",
  "publisher": null,
  "ris": "https://research.draconitic.com/paper/3s6351j1y5z6w.ris",
  "sources": [
    {
      "first_seen": "2026-11-01T12:23:09Z",
      "native_id": "PMC13715995",
      "source": "pmc",
      "url": "https://doi.org/10.1002/chem.71515"
    }
  ],
  "subjects": [
    {
      "field": "chemistry",
      "origin": "openalex:1605|Carbohydrate Chemistry and Synthesis",
      "subfield": "organic"
    }
  ],
  "title": "Stereoselective Synthesis of β‐C‐glycosides From Exoglycals Through Radical C─C Bond Formation",
  "title_text": "Stereoselective Synthesis of β‐C‐glycosides From Exoglycals Through Radical C─C Bond Formation",
  "type": "peer-reviewed",
  "updated_at": "2026-11-01T12:23:09Z",
  "url": "https://research.draconitic.com/paper/3s6351j1y5z6w",
  "venue": "Chemistry (Weinheim an Der Bergstrasse, Germany)",
  "versions": []
}