{
  "abstract": "Neutral heteroleptic trithiocyanurato-bridged manganese(i)/rhenium(i)-based M₃LL'-type trinuclear and M₆L₂L″-type hexanuclear metallacages were accomplished in a single step by one-pot synthesis strategy using rudimentary dimetal decacarbonyl (Mn₂(CO)₁₀/Re₂(CO)₁₀), flexible tripodal ligands (L' = 2-ethyl-2((isonicotinoyloxy)methyl)propane-1,3-diyl diisonicotinate (L₁) and 1,3,5-tri(benzimidazol-1-ylmethyl)-2,4,6-triethylbenzene (L₂)) or hexapodal N-donors (L″ = 1,2,3,4,5,6-hexakis(benzimidazol-1-ylmethyl)-benzene (L₃)) alongside of trithiocyanuric acid (L = ttcH₃) as a tris-N,S-chelating bridge via orthogonal bonding approach. The M₃LL' type trinuclear (1-4) and M₆L₂L″-type hexanuclear (5-6) metallacages were characterized by IR, UV/Vis, ¹H NMR spectroscopic and HR-ESI-MS techniques and elemental analysis. Furthermore, the structural elucidation by single-crystal X-ray diffraction techniques revealed a dome-shaped trinuclear metallacage for 1 and an Igloo-type trinuclear cage-like framework for 3 and 4, while the metallacage 6 displayed a hexanuclear hour glass type of architecture.",
  "abstract_shown": true,
  "affiliations": [
    "Department of Chemistry, Pondicherry University Puducherry 605014 India manimaran.che@pondiuni.ac.in.",
    "Department of Chemistry, Vellore Institute of Technology, Chennai Campus Vandalur- Kelambakkam Road Chennai Tamil Nadu 600127 India."
  ],
  "article_type": "research article",
  "arxiv": null,
  "author_total": 7,
  "authors": [
    {
      "affs": [
        0,
        1
      ],
      "name": "Buthanapalli Ramakrishna",
      "orcid": "0000-0002-8967-6167"
    },
    {
      "affs": [
        0
      ],
      "name": "Udit Kumar",
      "orcid": "0000-0001-8821-6436"
    },
    {
      "affs": [
        0
      ],
      "name": "Shruti Verma",
      "orcid": "0000-0002-5156-1794"
    },
    {
      "affs": [
        0
      ],
      "name": "Anupam Bhim"
    },
    {
      "affs": [
        0
      ],
      "name": "Suman Bhattacharya",
      "orcid": "0000-0001-9767-7779"
    },
    {
      "affs": [
        0
      ],
      "name": "Binoy Krishna Saha"
    },
    {
      "affs": [
        0
      ],
      "name": "Bala Manimaran",
      "orcid": "0000-0002-2974-4949"
    }
  ],
  "bibtex": "https://research.draconitic.com/paper/4495shm9qw6n0.bib",
  "cited_by": 0,
  "doi": "10.1039/d6ra04107h",
  "fulltext_url": "https://europepmc.org/articles/PMC13712455",
  "id": "4495shm9qw6n0",
  "issns": [
    "2046-2069"
  ],
  "landing_url": "https://europepmc.org/article/MED/42948757",
  "language": "eng",
  "licence": "CC-BY-NC",
  "licence_label": "CC BY-NC",
  "licence_source": "article",
  "licence_url": "https://creativecommons.org/licenses/by-nc/4.0/",
  "metadata_licence": null,
  "native_subjects": [
    [
      "heading",
      "Chemistry"
    ],
    [
      "openalex",
      "1605|Supramolecular Chemistry and Complexes"
    ]
  ],
  "openalex": "W7223942626",
  "pdf_url": "https://europepmc.org/articles/PMC13712455?pdf=render",
  "pmcid": "PMC13712455",
  "pmid": "42948757",
  "published": "2026-10-27",
  "publisher": "Royal Society of Chemistry",
  "ris": "https://research.draconitic.com/paper/4495shm9qw6n0.ris",
  "sources": [
    {
      "first_seen": "2026-10-31T00:20:33Z",
      "native_id": "MED:42948757",
      "source": "europepmc",
      "url": "https://europepmc.org/article/MED/42948757"
    },
    {
      "first_seen": "2026-10-31T12:23:01Z",
      "native_id": "PMC13712455",
      "source": "pmc",
      "url": "https://doi.org/10.1039/d6ra04107h"
    }
  ],
  "subjects": [
    {
      "field": "chemistry",
      "origin": "openalex:1605|Supramolecular Chemistry and Complexes",
      "subfield": "organic"
    }
  ],
  "title": "Multi-component self-assembled trithiocyanurato-bridged manganese(i)- and rhenium(i)-based diverse shaped tri- and hexanuclear metallacages.",
  "title_text": "Multi-component self-assembled trithiocyanurato-bridged manganese(i)- and rhenium(i)-based diverse shaped tri- and hexanuclear metallacages.",
  "type": "peer-reviewed",
  "updated_at": "2026-10-31T12:23:01Z",
  "url": "https://research.draconitic.com/paper/4495shm9qw6n0",
  "venue": "RSC advances",
  "versions": []
}