{
  "abstract": "Herein, we present a method for generating chlorine dioxide radical Alt-text is not available for this image. under solvent-free conditions by ball milling sodium chlorite with silica gel. The mechanochemical formation of Alt-text is not available for this image. was supported by UV-vis absorption spectroscopy and ESR measurements. The in situ-generated Alt-text is not available for this image. was directly used for the selective monooxygenation of dibenzothiophenes, including a poorly soluble π-extended benzothiophene derivative. This method provides a practical solvent-free platform for Alt-text is not available for this image.-mediated oxygenation of poorly soluble organosulfur compounds.",
  "abstract_shown": true,
  "affiliations": [
    "aGraduate School of Pharmaceutical Sciences, The University of Osaka, 1-6 Yamadaoka, Suita, Osaka 565-0871, Japan.",
    "bInstitute for Open and Transdisciplinary Research Initiatives (OTRI), The University of Osaka, 1-6 Yamadaoka, Suita, Osaka 565-0871, Japan.",
    "aGraduate School of Pharmaceutical Sciences, The University of Osaka, 1-6 Yamadaoka, Suita, Osaka 565-0871, Japan.bInstitute for Open and Transdisciplinary Research Initiatives (OTRI), The University of Osaka, 1-6 Yamadaoka, Suita, Osaka 565-0871, Japan.",
    "bInstitute for Open and Transdisciplinary Research Initiatives (OTRI), The University of Osaka, 1-6 Yamadaoka, Suita, Osaka 565-0871, Japan.cOrganization for Carbon Neutrality Collaboration (OCNC), The University of Osaka, 1-6 Yamadaoka, Suita, Osaka 565-0871, Japan."
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  "author_total": 5,
  "authors": [
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      "name": "Kensho Sekiguchi"
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      "name": "Yuki Itabashi",
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      "name": "Tsuyoshi Inoue"
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      "name": "Kei Ohkubo",
      "orcid": "0000-0001-8328-9249"
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      "name": "Haruyasu Asahara",
      "orcid": "0000-0002-1808-7373"
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  "bibtex": "https://research.draconitic.com/paper/4fgp5b6htgsw7.bib",
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  "doi": "10.1039/d6ra07225a",
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  "pmcid": "PMC13656216",
  "pmid": "42865941",
  "published": "2026-10-12",
  "publisher": "The Royal Society of Chemistry",
  "ris": "https://research.draconitic.com/paper/4fgp5b6htgsw7.ris",
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  "subjects": [
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      "field": "chemistry",
      "origin": "openalex:1605|Chemical Synthesis and Reactions",
      "subfield": "organic"
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  ],
  "title": "Mechanochemical generation of chlorine dioxide radical for solvent-free oxygenation of dibenzothiophenes",
  "title_text": "Mechanochemical generation of chlorine dioxide radical for solvent-free oxygenation of dibenzothiophenes",
  "type": "peer-reviewed",
  "updated_at": "2026-11-02T12:20:50Z",
  "url": "https://research.draconitic.com/paper/4fgp5b6htgsw7",
  "venue": "RSC advances",
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}