{
  "abstract": "Exploration of new arsenide-based infrared (IR) nonlinear optical (NLO) crystals has long been hindered by the narrow band gap limitations and the difficulty of achieving non-centrosymmetric (NCS) structures, despite their promising potential in the long-wave infrared region. By assembling MAs4 (M = Ga, In) tetrahedra and novel [As2] linear motifs, we designed and synthesized two new NCS arsenides, CaM3Si4As11 (M = Ga, In), featuring quasi-T3 M3Si4As11[As2]6 supertetrahedra decorated by [As2] motifs. CGSA and CISA exhibited strong SHG responses (1.7 and 2.5 × ZGP at 2900 nm), wide band gaps among arsenides (1.65 eV and 1.49 eV), broad IR transparency range (cutoff edge up to 12.5 µm), and large birefringence (0.122 and 0.128). Structure–property relationship analyses revealed that the wide band gap originated from the synergistic effect of the high average coordination number of As atoms induced by As–As bonding and the high excitation energy of SiAs4 tetrahedra. Furthermore, the [As2] motifs with highly polarizable π-interactions made a significant contribution to NLO effects and birefringence. This work demonstrates that arsenides with introduced [As2] units are promising systems for long-wave IR NLO materials.",
  "abstract_shown": true,
  "affiliations": [
    "State Key Laboratory of Crystal Materials, Tianjin Key Laboratory of Functional Crystal Materials, Institute of Functional Crystal, College of Materials Science and Engineering, Tianjin University of Technology Tianjin 300384 China",
    "Tianjin Key Laboratory of Quantum Optics and Intelligent Photonics, School of Science, Tianjin University of Technology Tianjin 300384 China"
  ],
  "article_type": "research article",
  "arxiv": null,
  "author_total": 6,
  "authors": [
    {
      "affs": [
        0
      ],
      "name": "Shusen Yang"
    },
    {
      "affs": [
        0
      ],
      "name": "Qichao Zhao"
    },
    {
      "affs": [
        0
      ],
      "name": "Xuemei Shi"
    },
    {
      "affs": [
        0,
        1
      ],
      "name": "Guang Peng",
      "orcid": "0000-0002-2092-8020"
    },
    {
      "affs": [
        0,
        1
      ],
      "name": "Ning Ye",
      "orcid": "0000-0002-3679-4047"
    },
    {
      "affs": [
        0,
        1
      ],
      "name": "Jindong Chen",
      "orcid": "0000-0002-3940-9968"
    }
  ],
  "bibtex": "https://research.draconitic.com/paper/4vas6p6xrmshb.bib",
  "cited_by": 0,
  "doi": "10.1039/d6sc04910a",
  "fulltext_url": "https://pmc.ncbi.nlm.nih.gov/articles/PMC13592203/",
  "id": "4vas6p6xrmshb",
  "issns": [
    "2041-6520",
    "2041-6539"
  ],
  "landing_url": "https://doi.org/10.1039/d6sc04910a",
  "language": "en",
  "licence": "CC-BY-NC-3.0",
  "licence_label": "CC BY-NC 3.0",
  "licence_source": "article",
  "licence_url": "https://creativecommons.org/licenses/by-nc/3.0/",
  "metadata_licence": null,
  "native_subjects": [
    [
      "heading",
      "Chemistry"
    ],
    [
      "openalex",
      "2504|Crystal Structures and Properties"
    ]
  ],
  "openalex": "W7212177401",
  "pdf_url": null,
  "pmcid": "PMC13592203",
  "pmid": "42770022",
  "published": "2026-09-10",
  "publisher": "Royal Society of Chemistry",
  "ris": "https://research.draconitic.com/paper/4vas6p6xrmshb.ris",
  "sources": [
    {
      "first_seen": "2026-11-07T12:23:30Z",
      "native_id": "PMC13592203",
      "source": "pmc",
      "url": "https://doi.org/10.1039/d6sc04910a"
    }
  ],
  "subjects": [
    {
      "field": "chemistry",
      "origin": "openalex:2504|Crystal Structures and Properties",
      "subfield": "materials-polymers"
    }
  ],
  "title": "CaM3Si4As11 (M = Ga, In): arsenide infrared nonlinear optical crystals enforced by novel [As2] linear motifs",
  "title_text": "CaM3Si4As11 (M = Ga, In): arsenide infrared nonlinear optical crystals enforced by novel [As2] linear motifs",
  "type": "peer-reviewed",
  "updated_at": "2026-11-08T12:20:59Z",
  "url": "https://research.draconitic.com/paper/4vas6p6xrmshb",
  "venue": "Chemical Science",
  "versions": []
}