{
  "abstract": "It remains a challenge to develop an ultrastable and single-crystalline photocatalyst with smart structural flexibility for the efficient capture and conversion of carbon dioxide. Herein, we report the reticular synthesis of a single-crystalline pyrazolate-based MOF (Pz-MOF)Zn-TPPexhibiting exceptional stability and stimuli-responsive structural dynamicsby the assembly of photosensitizing pyrene-based tetrapyrazolate linkers and zinc ions. Zn-TPP retains its crystallinity and porosity after high-temperature treatment over 400 °C or after immersion in basic aqueous conditions (5 M NaOH). The reversible dynamic behavior of Zn-TPP was unambiguously observed by single-crystal-to-single-crystal transition experiments. Thanks to the integration of photosensitizing pyrene units into this ultrastable and flexible porous platform, Zn-TPP displays efficient CO2 capture performance and is a reusable efficient photocatalyst for the reduction of CO2.",
  "abstract_shown": true,
  "affiliations": [
    "Stoddart Institute of Molecular Science, Department of Chemistry, Zhejiang Key Laboratory of Excited-State Energy Conversion and Energy Storage, State Key Laboratory of Silicon and Advanced Semiconductor Materials, Zhejiang University, Hangzhou 310058, P. R. China.",
    "Zhejiang-Israel Joint Laboratory of Self-Assembling Functional Materials, ZJU-Hangzhou Global Scientific and Technological Innovation Center, Zhejiang University, Hangzhou 311215, P. R. China.",
    "Changzhi Key Laboratory of Drug Molecular Design and Innovative Pharmaceutics, School of Pharmacy, Changzhi Medical College, Changzhi, Shanxi 046000, P. R. China.",
    "School of Chemistry and Chemical Engineering, Anhui University of Technology, Ma'anshan 243032, P. R. China.",
    "ICGM, CNRS, ENSCM, Univ. Montpellier, Montpellier 34090, France.",
    "Institut Universitaire de France, Paris 75005, France."
  ],
  "article_type": "research article",
  "arxiv": null,
  "author_total": 7,
  "authors": [
    {
      "affs": [
        0,
        1,
        2
      ],
      "name": "Guojuan Zhi"
    },
    {
      "affs": [
        0,
        1
      ],
      "name": "Mengyang Zhai"
    },
    {
      "affs": [
        3
      ],
      "name": "Dayang Cheng"
    },
    {
      "affs": [
        4
      ],
      "name": "Mohammad Wahiduzzaman",
      "orcid": "0000-0003-2025-4115"
    },
    {
      "affs": [
        4,
        5
      ],
      "name": "Guillaume Maurin",
      "orcid": "0000-0002-2096-0450"
    },
    {
      "affs": [
        3
      ],
      "name": "Guozan Yuan",
      "orcid": "0000-0003-0074-1274"
    },
    {
      "affs": [
        0,
        1
      ],
      "name": "Zhijie Chen",
      "orcid": "0000-0001-9232-7382"
    }
  ],
  "bibtex": "https://research.draconitic.com/paper/562fakmdmhdw1.bib",
  "cited_by": 0,
  "doi": "10.1021/prechem.6c00007",
  "fulltext_url": "https://europepmc.org/articles/PMC13715322",
  "id": "562fakmdmhdw1",
  "issns": [
    "2771-9316"
  ],
  "landing_url": "https://europepmc.org/article/MED/42953702",
  "language": "eng",
  "licence": "CC-BY-NC-ND",
  "licence_label": "CC BY-NC-ND",
  "licence_source": "article",
  "licence_url": "https://creativecommons.org/licenses/by-nc-nd/4.0/",
  "metadata_licence": null,
  "native_subjects": [
    [
      "heading",
      "Article"
    ],
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      "lcc",
      "QD1-999"
    ],
    [
      "openalex",
      "1604|Metal-Organic Frameworks: Synthesis and Applications"
    ]
  ],
  "openalex": "W7164131043",
  "pdf_url": "https://europepmc.org/articles/PMC13715322?pdf=render",
  "pmcid": "PMC13715322",
  "pmid": "42953702",
  "published": "2026-06-01",
  "publisher": "American Chemical Society",
  "ris": "https://research.draconitic.com/paper/562fakmdmhdw1.ris",
  "sources": [
    {
      "first_seen": "2026-10-31T00:20:41Z",
      "native_id": "MED:42953702",
      "source": "europepmc",
      "url": "https://europepmc.org/article/MED/42953702"
    },
    {
      "first_seen": "2026-10-31T14:21:14Z",
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      "url": "https://doi.org/10.1021/prechem.6c00007"
    },
    {
      "first_seen": "2026-11-01T12:22:39Z",
      "native_id": "PMC13715322",
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      "url": "https://doi.org/10.1021/prechem.6c00007"
    }
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  "subjects": [
    {
      "field": "chemistry",
      "origin": "openalex:1604|Metal-Organic Frameworks: Synthesis and Applications",
      "subfield": "inorganic"
    }
  ],
  "title": "Reticular Synthesis of Ultrastable Dynamic Zinc-Pyrazolate Frameworks for Efficient CO₂ Photoreduction.",
  "title_text": "Reticular Synthesis of Ultrastable Dynamic Zinc-Pyrazolate Frameworks for Efficient CO₂ Photoreduction.",
  "type": "peer-reviewed",
  "updated_at": "2026-11-01T12:22:39Z",
  "url": "https://research.draconitic.com/paper/562fakmdmhdw1",
  "venue": "Precision chemistry",
  "versions": []
}