{
  "abstract": "Metal-organic frameworks (MOFs) are widely explored for gas separation, catalysis or energy storage, yet their integration with other electronically functional materials remains largely unexplored. Here, we integrate the layered Hofmann-type spin-crossover (SCO) MOF {FeII(pyS2Et)2[PtII(CN)4]} into electrical nanodevices to control the properties of two-dimensional (2D) quantum materials. Our molecular approach exploits the stimuli-responsive nature of SCO layered materials as switchable building blocks. We demonstrate selective modulation of the electronic transport in van der Waals heterostructures interfacing SCO with 2D quantum materials (few-layer graphene, magnetic CrSBr, superconducting NbSe2) through the strain induced via thermal and light-induced spin transitions. In graphene, the conductivity is selectively switched by light. In spin-valves based on CrSBr bilayers, the MOF triggers magnetic hysteresis (absent in pristine CrSBr) and enables tunable non-volatile zero-field memory. In NbSe2, light modulates the superconducting critical current and transition temperature. These results establish layered stimuli-responsive SCO MOFs as active molecular control elements for 2D quantum materials, providing a route to strain-mediated control of electronic, magnetic, and superconducting functionalities and extending MOF-based architectures beyond traditional porous-matter applications towards multifunctional electronics and spintronics.",
  "abstract_shown": true,
  "affiliations": [],
  "article_type": "Journal reference: Advanced Materials 2026",
  "arxiv": "2610.07918",
  "author_total": 5,
  "authors": [
    {
      "name": "Carla Boix-Constant"
    },
    {
      "name": "Alejandro Orellana-Silla"
    },
    {
      "name": "José Antonio Real"
    },
    {
      "name": "Samuel Mañas-Valero"
    },
    {
      "name": "Eugenio Coronado"
    }
  ],
  "bibtex": "https://research.draconitic.com/paper/5j53yvqwhn3v0.bib",
  "cited_by": 0,
  "doi": "10.48550/arxiv.2610.07918",
  "fulltext_url": null,
  "id": "5j53yvqwhn3v0",
  "issns": [],
  "landing_url": "https://arxiv.org/abs/2610.07918",
  "language": null,
  "licence": "CC-BY-NC-SA-4.0",
  "licence_label": "CC BY-NC-SA 4.0",
  "licence_source": "article",
  "licence_url": "http://creativecommons.org/licenses/by-nc-sa/4.0/",
  "metadata_licence": "CC0-1.0",
  "native_subjects": [
    [
      "arxiv",
      "cond-mat.mtrl-sci"
    ],
    [
      "arxiv",
      "physics.chem-ph"
    ]
  ],
  "openalex": null,
  "pdf_url": "https://arxiv.org/pdf/2610.07918",
  "pmcid": null,
  "pmid": null,
  "published": "2026-10-06",
  "publisher": null,
  "ris": "https://research.draconitic.com/paper/5j53yvqwhn3v0.ris",
  "sources": [
    {
      "first_seen": "2026-10-30T12:27:22Z",
      "native_id": "2610.07918",
      "source": "arxiv",
      "url": "https://arxiv.org/abs/2610.07918"
    }
  ],
  "subjects": [
    {
      "field": "chemistry",
      "origin": "arxiv:physics.chem-ph",
      "subfield": "physical"
    },
    {
      "field": "physics",
      "origin": "arxiv:cond-mat.mtrl-sci",
      "subfield": "condensed-matter"
    }
  ],
  "title": "Layered spin-crossover metal-organic frameworks for light-induced control of two-dimensional quantum materials",
  "title_text": "Layered spin-crossover metal-organic frameworks for light-induced control of two-dimensional quantum materials",
  "type": "preprint",
  "updated_at": "2026-10-30T12:27:22Z",
  "url": "https://research.draconitic.com/paper/5j53yvqwhn3v0",
  "venue": "arXiv",
  "versions": [
    {
      "doi": "10.1002/adma.75351",
      "pid": null,
      "relation": "published-as",
      "title": null,
      "venue": null
    }
  ]
}