{
  "abstract": "Use of liquid films in liquid-phase focused electron beam induced deposition (LP-FEBID) can enable high growth rate and high purity nanostructure synthesis, but the height and aspect ratio of the deposits are limited by the liquid film thickness and by lateral spreading of reactive species. Here, we introduce a backscattered electron droplet-to-deposit (BSE-D2D) process in which a nanoelectrospray delivers metal-ion precursor containing droplets toward a grounded substrate inside a scanning electron microscope (SEM). The droplets are irradiated primarily by backscattered electrons emitted from the substrate during primary electron beam exposure. This irradiation drives radiolysis inside the droplets and reduces metal ions/ion-complexes to metal atoms before the droplets reach the substrate. Repeated delivery of these droplets leads to nanopillar growth in the direction of nanoelectrospray. The effect of electron energy on nanopillar growth was studied using Monte Carlo simulations, reaction-diffusion simulations, and experiments. Lower primary electron beam energies deliver higher backscattered electron dose to the droplets, leading to faster metal reduction and formation of larger metal nanoclusters that aggregate after reaching the substrate. At higher primary electron beam energies, lower dose delivery produces fewer and smaller reduced species, allowing metal atoms and small clusters to reorganize on the growing nanopillar into larger elongated grains. The visual invesitgation of experimentally obtained morphologies follow the proposed trend, showing a transition from nanocluster aggregation at lower energy to on-pillar metal reorganization at higher energy. These results show that BSE-D2D can extend liquid-phase FEBID to high-aspect-ratio metal nanostructures while using electron energy to influence morphology.",
  "abstract_shown": true,
  "affiliations": [
    "George W. Woodruff School of Mechanical Engineering, Georgia Institute of Technology Atlanta GA 30332 USA AGF@gatech.edu.",
    "Parker H. Petit Institute for Bioengineering and Biosciences, Georgia Institute of Technology Atlanta Georgia 30332 USA."
  ],
  "article_type": "research article",
  "arxiv": null,
  "author_total": 3,
  "authors": [
    {
      "affs": [
        0
      ],
      "name": "Auwais Ahmed",
      "orcid": "0000-0002-1120-985X"
    },
    {
      "affs": [
        0
      ],
      "name": "Muhamad Zakaria"
    },
    {
      "affs": [
        0,
        1
      ],
      "name": "Andrei G Fedorov",
      "orcid": "0000-0003-0859-2541"
    }
  ],
  "bibtex": "https://research.draconitic.com/paper/5q5wbjphve27d.bib",
  "cited_by": 0,
  "doi": "10.1039/d6na00760k",
  "fulltext_url": "https://europepmc.org/articles/PMC13741222",
  "id": "5q5wbjphve27d",
  "issns": [
    "2516-0230"
  ],
  "landing_url": "https://europepmc.org/article/MED/42997207",
  "language": "eng",
  "licence": "CC-BY-NC",
  "licence_label": "CC BY-NC",
  "licence_source": "article",
  "licence_url": "https://creativecommons.org/licenses/by-nc/4.0/",
  "metadata_licence": null,
  "native_subjects": [
    [
      "openalex",
      "2508|Nanofabrication and Lithography Techniques"
    ]
  ],
  "openalex": "W7225376140",
  "pdf_url": "https://europepmc.org/articles/PMC13741222?pdf=render",
  "pmcid": "PMC13741222",
  "pmid": "42997207",
  "published": "2026-11-06",
  "publisher": null,
  "ris": "https://research.draconitic.com/paper/5q5wbjphve27d.ris",
  "sources": [
    {
      "first_seen": "2026-11-09T15:20:34Z",
      "native_id": "MED:42997207",
      "source": "europepmc",
      "url": "https://europepmc.org/article/MED/42997207"
    }
  ],
  "subjects": [
    {
      "field": "chemistry",
      "origin": "openalex:2508|Nanofabrication and Lithography Techniques",
      "subfield": "materials-polymers"
    }
  ],
  "title": "Droplet-to-deposit nanostructure synthesis in a fountain of backscattered electrons.",
  "title_text": "Droplet-to-deposit nanostructure synthesis in a fountain of backscattered electrons.",
  "type": "peer-reviewed",
  "updated_at": "2026-11-09T15:20:34Z",
  "url": "https://research.draconitic.com/paper/5q5wbjphve27d",
  "venue": "Nanoscale advances",
  "versions": []
}