{
  "abstract": "Three dimensional linkers are rare in MOF chemistry, as are linkers featuring inorganic elements. Here we report the synthesis and characterisation of a novel phosphorus-nitrogen (PN) cage-based tetra-benzoic acid (P4BA4) and its use for the synthesis of crystalline framework materials PNMOF-1 and PNHOF-1. These results expand the toolkit of 3-dimensional inorganic linkers beyond the current state of the art defined by carboranes and silsequioxanes.",
  "abstract_shown": true,
  "affiliations": [
    "Department of Chemistry, University of Victoria, 4800 Finnerty Road, Victoria, BC, Canada, V8P 5C2",
    "Department of Chemistry, Dalhousie University, 6243 Alumni Crescent, Halifax, NS, Canada, B3H 4R2"
  ],
  "article_type": null,
  "arxiv": null,
  "author_total": 5,
  "authors": [
    {
      "affs": [
        0
      ],
      "name": "Pinelopi A. Tsami"
    },
    {
      "affs": [
        0
      ],
      "name": "Ethan Trenaman"
    },
    {
      "affs": [
        0
      ],
      "name": "Anjali Nambidiyattil"
    },
    {
      "affs": [
        1
      ],
      "name": "Mohsen Shayan"
    },
    {
      "affs": [
        0,
        1
      ],
      "name": "Saurabh S. Chitnis",
      "orcid": "0000-0001-9180-7907"
    }
  ],
  "bibtex": "https://research.draconitic.com/paper/5sbywdzrssb6d.bib",
  "cited_by": 0,
  "doi": "10.26434/chemrxiv.15009518/v1",
  "fulltext_url": null,
  "id": "5sbywdzrssb6d",
  "issns": [],
  "landing_url": "https://chemrxiv.org/doi/full/10.26434/chemrxiv.15009518/v1",
  "language": null,
  "licence": "CC-BY",
  "licence_label": "CC BY",
  "licence_source": "journal",
  "licence_url": "https://creativecommons.org/licenses/by/4.0/",
  "metadata_licence": null,
  "native_subjects": [
    [
      "openalex",
      "1604|Metal-Organic Frameworks: Synthesis and Applications"
    ]
  ],
  "openalex": "W7214652160",
  "pdf_url": null,
  "pmcid": null,
  "pmid": null,
  "published": "2026-09-28",
  "publisher": "American Chemical Society (ACS)",
  "ris": "https://research.draconitic.com/paper/5sbywdzrssb6d.ris",
  "sources": [
    {
      "first_seen": "2026-10-30T12:17:21Z",
      "native_id": "10.26434/chemrxiv.15009518",
      "source": "chemrxiv",
      "url": "https://chemrxiv.org/doi/full/10.26434/chemrxiv.15009518/v2"
    }
  ],
  "subjects": [
    {
      "field": "chemistry",
      "origin": "openalex:1604|Metal-Organic Frameworks: Synthesis and Applications",
      "subfield": "inorganic"
    }
  ],
  "title": "A PN adamantanoid ligand for reticular materials",
  "title_text": "A PN adamantanoid ligand for reticular materials",
  "type": "preprint",
  "updated_at": "2026-10-30T12:17:22Z",
  "url": "https://research.draconitic.com/paper/5sbywdzrssb6d",
  "venue": "ChemRxiv",
  "versions": []
}