{
  "abstract": "The title complex, [Ru(C7H4N2)2(C10H14)(C3H9P)] or (p-cym)Ru(C2-2py)2(PMe3), where p-cym = η6-1-isopropyl-4-methyl-benzene and C2-2py = η1-C-pyridin-2-ylethynide, comprises a pseudo-octa-hedral RuII atom with p-cym occupying one face of the octa-hedron and the other face comprised of monodentate PMe3 and two η1-C2-2py ligands. The Ru-Cethynide bond lengths are 2.0248 (16) and 2.0343 (17) Å. The N-C-C-N torsion angle of 151.1 (2)° suggests a near anti-conformation for the two pyridine rings. In the crystal, hydrogen bonding involving one C-H donor and one nitro-gen acceptor from each pyridine ring generates dimers propagating along the a-axis direction via supporting C-H⋯π inter-actions.",
  "abstract_shown": true,
  "affiliations": [
    "The University of Tennessee at Chattanooga Department of Chemistry #2252 615 McCallie Avenue Chattanooga TN 37403 USA.",
    "Clemson University, Department of Chemistry, Clemson, SC 29634, USA."
  ],
  "article_type": "research article",
  "arxiv": null,
  "author_total": 5,
  "authors": [
    {
      "affs": [
        0
      ],
      "name": "Bre-Anna N Willis"
    },
    {
      "affs": [
        0
      ],
      "name": "Aaron Meeks"
    },
    {
      "affs": [
        1
      ],
      "name": "Colin D McMillen"
    },
    {
      "affs": [
        0
      ],
      "name": "Jared A Pienkos"
    },
    {
      "affs": [
        0
      ],
      "name": "John P Lee",
      "orcid": "0000-0002-4245-5260"
    }
  ],
  "bibtex": "https://research.draconitic.com/paper/5svmvvs7tfj9j.bib",
  "cited_by": 0,
  "doi": "10.1107/s241431462601045x",
  "fulltext_url": "https://europepmc.org/articles/PMC13741267",
  "id": "5svmvvs7tfj9j",
  "issns": [
    "2414-3146"
  ],
  "landing_url": "https://europepmc.org/article/MED/42997277",
  "language": "eng",
  "licence": "CC-BY",
  "licence_label": "CC BY",
  "licence_source": "article",
  "licence_url": "https://creativecommons.org/licenses/by/4.0/",
  "metadata_licence": null,
  "native_subjects": [
    [
      "openalex",
      "1604|Crystal structures of chemical compounds"
    ]
  ],
  "openalex": "W7222999763",
  "pdf_url": "https://europepmc.org/articles/PMC13741267?pdf=render",
  "pmcid": "PMC13741267",
  "pmid": "42997277",
  "published": "2026-09-01",
  "publisher": null,
  "ris": "https://research.draconitic.com/paper/5svmvvs7tfj9j.ris",
  "sources": [
    {
      "first_seen": "2026-11-09T15:20:42Z",
      "native_id": "MED:42997277",
      "source": "europepmc",
      "url": "https://europepmc.org/article/MED/42997277"
    }
  ],
  "subjects": [
    {
      "field": "chemistry",
      "origin": "openalex:1604|Crystal structures of chemical compounds",
      "subfield": "inorganic"
    }
  ],
  "title": "(η⁶-1-Isopropyl-4-methyl-benzene)-bis-(η¹-pyridin-2-ylethynido-κC)(tri-methyl-phosphane-κP)ruthenium(II).",
  "title_text": "(η⁶-1-Isopropyl-4-methyl-benzene)-bis-(η¹-pyridin-2-ylethynido-κC)(tri-methyl-phosphane-κP)ruthenium(II).",
  "type": "peer-reviewed",
  "updated_at": "2026-11-09T15:20:42Z",
  "url": "https://research.draconitic.com/paper/5svmvvs7tfj9j",
  "venue": "IUCrData",
  "versions": []
}