{
  "abstract": "The reaction of the P,C,P‐pincer indium(III) chloride ArInCl2 with 2 eq. of K[BEt3H] provided crystalline monomeric indane ArInH2 (1) (Ar = 2,6‐(tBu2PO)2C6H3) bearing two terminal In─H bonds. Indane 1 is a multitalented reagent that serves as a reductant toward dichalcogenides (PhE)2 giving ArIn(EPh)2 (2E, E = S, Se, Te) or a hydride source in reaction with 4‐CF3‐C6H4OH that gives mono‐ or disubstituted indium phenolates ArIn(H)(4‐CF3‐C6H4O) (3), ArIn(4‐CF3‐C6H4O)2 (4) depending on stoichiometry. Most importantly, 1 is an unprecedented double hydroindation agent, as illustrated by its reactions with aldehydes 4‐R‐C6H4CHO (R = OMe, CF3, F) yielding ArIn(4‐R‐C6H4CH2O)2 (5R) or ketene Ph2C═C═O providing ArIn(Ph2C═CH─O)2 (6).",
  "abstract_shown": true,
  "affiliations": [
    "Department of General and Inorganic Chemistry Faculty of Chemical Technology University of Pardubice Pardubice Czech Republic"
  ],
  "article_type": "research article",
  "arxiv": null,
  "author_total": 6,
  "authors": [
    {
      "affs": [
        0
      ],
      "name": "Adam Hochmal",
      "orcid": "0009-0007-0009-1458"
    },
    {
      "affs": [
        0
      ],
      "name": "Zdeňka Růžičková"
    },
    {
      "affs": [
        0
      ],
      "name": "Aleš Růžička",
      "orcid": "0000-0001-8191-0273"
    },
    {
      "affs": [
        0
      ],
      "name": "Roman Jambor",
      "orcid": "0000-0002-3639-7631"
    },
    {
      "affs": [
        0
      ],
      "name": "Milan Erben",
      "orcid": "0000-0002-6712-8426"
    },
    {
      "affs": [
        0
      ],
      "name": "Libor Dostál",
      "orcid": "0000-0002-5982-1239"
    }
  ],
  "bibtex": "https://research.draconitic.com/paper/7dsg8qmtgachy.bib",
  "cited_by": 0,
  "doi": "10.1002/chem.71528",
  "fulltext_url": "https://pmc.ncbi.nlm.nih.gov/articles/PMC13716015/",
  "id": "7dsg8qmtgachy",
  "issns": [
    "0947-6539",
    "1521-3765"
  ],
  "landing_url": "https://doi.org/10.1002/chem.71528",
  "language": "en",
  "licence": "CC-BY-NC-4.0",
  "licence_label": "CC BY-NC 4.0",
  "licence_source": "article",
  "licence_url": "https://creativecommons.org/licenses/by-nc/4.0/",
  "metadata_licence": null,
  "native_subjects": [
    [
      "heading",
      "Research Article"
    ],
    [
      "openalex",
      "1604|Synthesis and characterization of novel inorganic/organometallic compounds"
    ]
  ],
  "openalex": "W7172286696",
  "pdf_url": null,
  "pmcid": "PMC13716015",
  "pmid": "42545891",
  "published": "2026-08-03",
  "publisher": null,
  "ris": "https://research.draconitic.com/paper/7dsg8qmtgachy.ris",
  "sources": [
    {
      "first_seen": "2026-11-01T12:23:10Z",
      "native_id": "PMC13716015",
      "source": "pmc",
      "url": "https://doi.org/10.1002/chem.71528"
    }
  ],
  "subjects": [
    {
      "field": "chemistry",
      "origin": "openalex:1604|Synthesis and characterization of novel inorganic/organometallic compounds",
      "subfield": "inorganic"
    }
  ],
  "title": "Isolable ArInH2: Double Hydroindation Agent",
  "title_text": "Isolable ArInH2: Double Hydroindation Agent",
  "type": "peer-reviewed",
  "updated_at": "2026-11-01T12:23:10Z",
  "url": "https://research.draconitic.com/paper/7dsg8qmtgachy",
  "venue": "Chemistry (Weinheim an Der Bergstrasse, Germany)",
  "versions": []
}