{
  "abstract": "Hydrogen-bonded ionic-pair frameworks (HIPFs) provide a versatile platform for controlling interfacial hydration through molecular organization. Here, two crystalline melamine-trimesic acid (ME-TMA) HIPFs structures with fiber-like and plate-like morphologies, denoted F-HIPF and P-HIPF, were obtained by varying the nucleation conditions. Both materials exhibit low N2-accessible surface areas of 7.5 and 2.5 m2 g-1, respectively, providing a low-porosity platform in which hydration behavior can be separated from extensive permanent-pore filling. F-HIPF shows smooth, nearly reversible water uptake, whereas P-HIPF develops pronounced high-humidity hysteresis associated with more cooperative water retention. Direct, water-vapor adsorption and desorption, calorimetry reveals distinct loading-dependent enthalpic and entropic signatures. Operando difference infrared spectroscopy further demonstrates reversible hydration and different temperature dependences of the normalized initial response. Rate-derived kinetic descriptors indicate an enthalpically favorable but entropically penalized response for F-HIPF and an almost athermal, kinetically entropy-favored response for P-HIPF. When deposited on oxidized carbon fibers, F-HIPF increases irradiation-induced evaporation relative to bare CF, showing that a developed permanent pore network is not required for the observed enhancement.",
  "abstract_shown": true,
  "affiliations": [
    "Department of Materials Chemistry, Adsorption and Catalysis, Faculty of Chemistry, Nicolaus Copernicus University in Toruń, Gagarina 7, 87-100Toruń, Poland.",
    "Institute of Advanced Studies, Nicolaus Copernicus University in Toruń, Wileńska 4, 87-100Toruń, Poland."
  ],
  "article_type": "research article",
  "arxiv": null,
  "author_total": 1,
  "authors": [
    {
      "affs": [
        0,
        1
      ],
      "name": "Marek Wiśniewski",
      "orcid": "0000-0003-3478-5371"
    }
  ],
  "bibtex": "https://research.draconitic.com/paper/7khjpkgke8ay4.bib",
  "cited_by": 0,
  "doi": "10.1021/acs.langmuir.6c03562",
  "fulltext_url": "https://europepmc.org/articles/PMC13629667",
  "id": "7khjpkgke8ay4",
  "issns": [
    "0743-7463",
    "1520-5827"
  ],
  "landing_url": "https://europepmc.org/article/MED/42916833",
  "language": "eng",
  "licence": "CC-BY",
  "licence_label": "CC BY",
  "licence_source": "article",
  "licence_url": "https://creativecommons.org/licenses/by/4.0/",
  "metadata_licence": null,
  "native_subjects": [
    [
      "openalex",
      "2505|Covalent Organic Framework Applications"
    ]
  ],
  "openalex": "W7213547314",
  "pdf_url": "https://europepmc.org/articles/PMC13629667?pdf=render",
  "pmcid": "PMC13629667",
  "pmid": "42916833",
  "published": "2026-09-01",
  "publisher": null,
  "ris": "https://research.draconitic.com/paper/7khjpkgke8ay4.ris",
  "sources": [
    {
      "first_seen": "2026-10-30T12:21:02Z",
      "native_id": "MED:42916833",
      "source": "europepmc",
      "url": "https://europepmc.org/article/MED/42916833"
    }
  ],
  "subjects": [
    {
      "field": "chemistry",
      "origin": "openalex:2505|Covalent Organic Framework Applications",
      "subfield": "materials-polymers"
    }
  ],
  "title": "Suppressing Cooperative Water Condensation through Nucleation-Controlled HIPF Architectures.",
  "title_text": "Suppressing Cooperative Water Condensation through Nucleation-Controlled HIPF Architectures.",
  "type": "peer-reviewed",
  "updated_at": "2026-10-30T12:21:02Z",
  "url": "https://research.draconitic.com/paper/7khjpkgke8ay4",
  "venue": "Langmuir : the ACS journal of surfaces and colloids",
  "versions": []
}