{
  "abstract": "Non‐Arrhenius ion transport is increasingly observed in solid electrolytes but remains difficult to compare across materials or use in screening. A curated database of 867 conductivity‐temperature entries from thio‐LISICON and LGPS‐type sulfides is used to introduce Meyer–Neldel deviation (MND), a physics‐informed, material‐level descriptor of temperature‐dependent changes in apparent activation energy. More than 40% of the analyzed sulfide electrolytes show notable deviations from linear Arrhenius behavior. MND separates low‐conductivity/high‐barrier and superionic/low‐barrier regimes associated with ionic‐radius mismatch, electronegativity difference, configurational entropy, and mixing thermodynamics, while providing a more informative learning target than single‐value activation energies. Sensitivity analyses indicate that material‐level trends remain reasonably robust to variations in conductivity, reference temperature, and sampling density. Application to a reprocessed dataset of 160 compositions and 2,410 conductivity‐temperature entries across seven electrolyte families supports broader applicability. MND‐guided screening of 171 Li10Ge x Si y Sn z P2S12 compositions prioritizes Li10Ge0.3Si0.15Sn0.55P2S12, which exhibits a room‐temperature conductivity of 7.21 mS cm− 1, an apparent activation energy of 0.288 eV, and weak non‐Arrhenius behavior consistent with prediction. Evaluation of a second composition further supports the multistage screening strategy. These results position MND as a chemically interpretable representation for quantifying, learning, and screening temperature‐dependent ion transport.",
  "abstract_shown": true,
  "affiliations": [
    "Institute of Energy Technologies – Fundamental Electrochemistry (IET‐1) Forschungszentrum Jülich Jülich Germany",
    "Institute of Physical Chemistry RWTH Aachen University Aachen Germany",
    "College of Energy Xiamen University Xiamen China",
    "High Power Research Laboratory Sparks Nevada USA",
    "Faculty of Mechanical Engineering RWTH Aachen University Aachen Germany"
  ],
  "article_type": "research article",
  "arxiv": null,
  "author_total": 7,
  "authors": [
    {
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        0,
        1
      ],
      "name": "Han Zhou",
      "orcid": "0000-0003-4799-6610"
    },
    {
      "affs": [
        0
      ],
      "name": "Xiaoxuan Chen",
      "orcid": "0000-0002-3136-8153"
    },
    {
      "affs": [
        0
      ],
      "name": "Hermann Tempel",
      "orcid": "0000-0002-9794-6403"
    },
    {
      "affs": [
        2
      ],
      "name": "Yong Yang",
      "orcid": "0000-0002-9928-7165"
    },
    {
      "affs": [
        0,
        3
      ],
      "name": "Boryann Liaw",
      "orcid": "0000-0001-7431-1977"
    },
    {
      "affs": [
        0
      ],
      "name": "Shicheng Yu",
      "orcid": "0000-0002-6619-3330"
    },
    {
      "affs": [
        0,
        1,
        4
      ],
      "name": "Rüdiger‐A. Eichel",
      "orcid": "0000-0002-0013-6325"
    }
  ],
  "bibtex": "https://research.draconitic.com/paper/7sq8as14yfr5c.bib",
  "cited_by": 0,
  "doi": "10.1002/anie.4940262",
  "fulltext_url": "https://pmc.ncbi.nlm.nih.gov/articles/PMC13725577/",
  "id": "7sq8as14yfr5c",
  "issns": [
    "1433-7851",
    "1521-3773"
  ],
  "landing_url": "https://doi.org/10.1002/anie.4940262",
  "language": "en",
  "licence": "CC-BY-4.0",
  "licence_label": "CC BY 4.0",
  "licence_source": "article",
  "licence_url": "https://creativecommons.org/licenses/by/4.0/",
  "metadata_licence": null,
  "native_subjects": [
    [
      "heading",
      "Research Article"
    ],
    [
      "openalex",
      "2208|Advanced Battery Materials and Technologies"
    ]
  ],
  "openalex": "W7167019635",
  "pdf_url": null,
  "pmcid": "PMC13725577",
  "pmid": "42762443",
  "published": "2026-09-19",
  "publisher": null,
  "ris": "https://research.draconitic.com/paper/7sq8as14yfr5c.ris",
  "sources": [
    {
      "first_seen": "2026-11-04T12:23:56Z",
      "native_id": "PMC13725577",
      "source": "pmc",
      "url": "https://doi.org/10.1002/anie.4940262"
    }
  ],
  "subjects": [
    {
      "field": "chemistry",
      "origin": "journal-openalex:1605|Supramolecular Chemistry and Complexes",
      "subfield": "organic"
    }
  ],
  "title": "A Descriptor for Non‐Arrhenius Ion Transport Enables Design of Sulfide Superionic Conductors",
  "title_text": "A Descriptor for Non‐Arrhenius Ion Transport Enables Design of Sulfide Superionic Conductors",
  "type": "peer-reviewed",
  "updated_at": "2026-11-05T12:22:08Z",
  "url": "https://research.draconitic.com/paper/7sq8as14yfr5c",
  "venue": "Angewandte Chemie (International Ed. in English)",
  "versions": []
}