{
  "abstract": "A microwave-promoted iminyl radical cascade cyclization that furnishes semisaturated polycycles is reported. Competitive reduction was suppressed by lowering the reaction concentration. The protocol is simple and tolerates a wide range of O -aryloxime substrates, with those bearing an electron-withdrawing group on the participating aryl ring performing the best. The modular substrate synthesis renders the process useful for constructing compound libraries.",
  "abstract_shown": true,
  "affiliations": [
    "Department of Chemistry and Biochemistry",
    "Brigham Young University"
  ],
  "article_type": null,
  "arxiv": null,
  "author_total": 7,
  "authors": [
    {
      "affs": [
        0,
        1
      ],
      "name": "Caleb J. Petersen"
    },
    {
      "affs": [
        0,
        1
      ],
      "name": "Joshua D. Morgan"
    },
    {
      "affs": [
        0,
        1
      ],
      "name": "Corbin D. Stratton"
    },
    {
      "affs": [
        0,
        1
      ],
      "name": "Tanner A. Trejo"
    },
    {
      "affs": [
        0,
        1
      ],
      "name": "Ethan P. Downing"
    },
    {
      "affs": [
        0,
        1
      ],
      "name": "Jonathan J. Barker"
    },
    {
      "affs": [
        0,
        1
      ],
      "name": "Steven L. Castle",
      "orcid": "0000-0002-7837-4964"
    }
  ],
  "bibtex": "https://research.draconitic.com/paper/853whjg0r4rq5.bib",
  "cited_by": 0,
  "doi": "10.26434/chemrxiv.15009695/v1",
  "fulltext_url": null,
  "id": "853whjg0r4rq5",
  "issns": [],
  "landing_url": "https://chemrxiv.org/doi/full/10.26434/chemrxiv.15009695/v1",
  "language": null,
  "licence": "CC-BY-NC-ND",
  "licence_label": "CC BY-NC-ND",
  "licence_source": "journal",
  "licence_url": "https://creativecommons.org/licenses/by-nc-nd/4.0/",
  "metadata_licence": null,
  "native_subjects": [
    [
      "openalex",
      "1605|Radical Photochemical Reactions"
    ]
  ],
  "openalex": "W7214907004",
  "pdf_url": "https://chemrxiv.org/doi/pdf/10.26434/chemrxiv.15009695/v1",
  "pmcid": null,
  "pmid": null,
  "published": "2026-09-30",
  "publisher": "American Chemical Society (ACS)",
  "ris": "https://research.draconitic.com/paper/853whjg0r4rq5.ris",
  "sources": [
    {
      "first_seen": "2026-10-30T12:17:21Z",
      "native_id": "10.26434/chemrxiv.15009695",
      "source": "chemrxiv",
      "url": "https://chemrxiv.org/doi/full/10.26434/chemrxiv.15009695/v1"
    }
  ],
  "subjects": [
    {
      "field": "chemistry",
      "origin": "openalex:1605|Radical Photochemical Reactions",
      "subfield": "organic"
    }
  ],
  "title": "Synthesis of Semisaturated Polycycles via a Microwave-Promoted Iminyl Radical Cascade Cyclization",
  "title_text": "Synthesis of Semisaturated Polycycles via a Microwave-Promoted Iminyl Radical Cascade Cyclization",
  "type": "preprint",
  "updated_at": "2026-10-30T12:17:21Z",
  "url": "https://research.draconitic.com/paper/853whjg0r4rq5",
  "venue": "ChemRxiv",
  "versions": []
}