{
  "abstract": "The synthesis, structures, magnetic and luminescent properties of a new series of mononuclear Tb3+ complexes, such as {Tb[OCH(CF3)Ph]2(THF)5}[BPh4], [Tb(OC6F4C6F5)2(THF)5][BPh4], {Tb[OC(CF3)2Ph]2(THF)4} [BPh4] and {Tb[OC(CF3)3]3(THF)3}, in which fluorinated alkoxide ligands with different steric bulk afford different geometries of the Tb center, are reported. The compound {Tb[OCH(CF3)Ph]2(THF)5}[BPh4], which adopts a pentagonal bipyramidal geometry with an axial O–Tb–O angle of 177.7(5)° and short Tb–O distances, behaves as a field-induced single molecule magnet. All complexes exhibit characteristic Tb3+ emission with a relatively long lifetime of up to 1.7 ms.",
  "abstract_shown": true,
  "affiliations": [],
  "article_type": null,
  "arxiv": null,
  "author_total": 14,
  "authors": [
    {
      "name": "Dmitry Mikhailovich Lyubov"
    },
    {
      "name": "Gautier Félix"
    },
    {
      "name": "Aleksey O. Tolpygin"
    },
    {
      "name": "Tatyana V. Mahrova"
    },
    {
      "name": "Yulia Vladimirovna Nelyubina"
    },
    {
      "name": "Saad Sene"
    },
    {
      "name": "Vladislav Mikailovich Korshunov"
    },
    {
      "name": "Il'Ya Il'Ya Viktorovich Taidakov"
    },
    {
      "name": "Andrey Aleksandrovich Tyutyunov"
    },
    {
      "name": "Boris Le Guennic"
    },
    {
      "name": "Olivier Cador"
    },
    {
      "name": "Yannick Guari"
    },
    {
      "name": "Joulia Larionova"
    },
    {
      "name": "Aleksandr Anatol'Evich Trifonov"
    }
  ],
  "bibtex": "https://research.draconitic.com/paper/87djbr51y3hxk.bib",
  "cited_by": 1,
  "doi": "10.71267/mencom.7860",
  "fulltext_url": null,
  "id": "87djbr51y3hxk",
  "issns": [
    "0959-9436",
    "1364-551X"
  ],
  "landing_url": "https://hal.science/hal-05381548v1",
  "language": "en",
  "licence": "CC-BY-NC-SA-4.0",
  "licence_label": "CC BY-NC-SA 4.0",
  "licence_source": "article",
  "licence_url": "https://creativecommons.org/licenses/by-nc-sa/4.0/",
  "metadata_licence": null,
  "native_subjects": [
    [
      "hal",
      "0.chim"
    ],
    [
      "openalex",
      "2505|Lanthanide and Transition Metal Complexes"
    ]
  ],
  "openalex": "W4415383265",
  "pdf_url": "https://hal.science/hal-05381548/document",
  "pmcid": null,
  "pmid": null,
  "published": "2026-10-02",
  "publisher": "Elsevier",
  "ris": "https://research.draconitic.com/paper/87djbr51y3hxk.ris",
  "sources": [
    {
      "first_seen": "2026-10-30T12:17:46Z",
      "native_id": "hal-05381548",
      "source": "hal",
      "url": "https://hal.science/hal-05381548v1"
    }
  ],
  "subjects": [
    {
      "field": "chemistry",
      "origin": "openalex:2505|Lanthanide and Transition Metal Complexes",
      "subfield": "materials-polymers"
    }
  ],
  "title": "Slow relaxation of magnetization and luminescence in seven- and six-coordinate Tbandlt-supandgt-3+ andlt-/supandgt-complexes",
  "title_text": "Slow relaxation of magnetization and luminescence in seven- and six-coordinate Tbandlt-supandgt-3+ andlt-/supandgt-complexes",
  "type": "peer-reviewed",
  "updated_at": "2026-10-30T12:17:46Z",
  "url": "https://research.draconitic.com/paper/87djbr51y3hxk",
  "venue": "Mendeleev Communications",
  "versions": []
}