{
  "abstract": "Depending on the synthetic approach of the incorporation of fluorenylidenemalononitrile (L2) into a coordination polymer (CP), two different outcomes can be attained. In one case (UDS-6, [Cu2Br2(L2)2]n), the material turns out to be a photo-redox-active system with competing photophysical processes (1M/XLCT NIR emission, exciton migration and electron transfer), leading to tentative photovoltaic applications. In the other case, the hereby synthesized CP1 using a mono-cationic preassembly [Cu3(L1)2(Br)2]+ (L1 = bis(diphenylphosphinomethyl)phenylphosphine) turns out to be a visible 3M/XLCT emitter, as confirmed by extensive photophysical studies and theoretical investigations (DFT, TD-DFT, PW-DFT). Concurrently, this CP is found to be useful towards the photosensitization of singlet oxygen (¹Δg), as confirmed by the observation of the latter's intense phosphorescence signal at 1275 nm at the solid–gas interface. The dye degradation (rhodamine-6G) ability of CP1 was assessed but is limited by the rationalized instability of the material towards water",
  "abstract_shown": true,
  "affiliations": [],
  "article_type": null,
  "arxiv": null,
  "author_total": 5,
  "authors": [
    {
      "name": "Léo Boivin"
    },
    {
      "name": "Adrien Schlachter"
    },
    {
      "name": "Vincent Dorcet"
    },
    {
      "name": "Christophe Lescop"
    },
    {
      "name": "Pierre D Harvey"
    }
  ],
  "bibtex": "https://research.draconitic.com/paper/8cra85k494mbj.bib",
  "cited_by": 0,
  "doi": "10.1039/d6dt01974a",
  "fulltext_url": null,
  "id": "8cra85k494mbj",
  "issns": [
    "1477-9226",
    "1477-9234"
  ],
  "landing_url": "https://hal.science/hal-05857047v1",
  "language": "en",
  "licence": "CC-BY-4.0",
  "licence_label": "CC BY 4.0",
  "licence_source": "article",
  "licence_url": "https://creativecommons.org/licenses/by/4.0/",
  "metadata_licence": null,
  "native_subjects": [
    [
      "hal",
      "0.chim"
    ],
    [
      "hal",
      "1.chim.coor"
    ],
    [
      "hal",
      "1.chim.poly"
    ],
    [
      "hal",
      "1.chim.theo"
    ],
    [
      "openalex",
      "1604|Metal-Organic Frameworks: Synthesis and Applications"
    ]
  ],
  "openalex": "W7225430077",
  "pdf_url": "https://hal.science/hal-05857047/document",
  "pmcid": null,
  "pmid": null,
  "published": "2026-11-06",
  "publisher": "Royal Society of Chemistry",
  "ris": "https://research.draconitic.com/paper/8cra85k494mbj.ris",
  "sources": [
    {
      "first_seen": "2026-11-09T12:20:29Z",
      "native_id": "hal-05857047",
      "source": "hal",
      "url": "https://hal.science/hal-05857047v1"
    }
  ],
  "subjects": [
    {
      "field": "chemistry",
      "origin": "hal:1.chim.coor",
      "subfield": "inorganic"
    },
    {
      "field": "chemistry",
      "origin": "hal:1.chim.poly",
      "subfield": "materials-polymers"
    },
    {
      "field": "chemistry",
      "origin": "hal:1.chim.theo",
      "subfield": "theoretical"
    }
  ],
  "title": "Design-dependent properties and applications of copper(I) bromide and fluorenylidene malononitrile coordination polymers",
  "title_text": "Design-dependent properties and applications of copper(I) bromide and fluorenylidene malononitrile coordination polymers",
  "type": "peer-reviewed",
  "updated_at": "2026-11-09T12:20:29Z",
  "url": "https://research.draconitic.com/paper/8cra85k494mbj",
  "venue": "Dalton Transactions",
  "versions": []
}