{
  "abstract": "A one-pot solvothermal strategy has been used for the synthesis of two new series of isostructural coordination polymers based on the use of M = Co2+, Ni2+, Cu2+ or Zn2+ ions, dipyridyl alloxazine appended ligands L, and trans-stilbene-4,4′-dicarboxylate (stdc2−) or trans-azobenzene-4,4′-dicarboxylate (azbdc2−) linkers. Single-crystal X-ray diffraction (M = Zn2+) revealed that the resulting compounds, formulated as [M2(stdc)2L] (1-M) or [M2(azbdc)2L] (2-M) (M = Co, Ni, Cu or Zn), comprise two-dimensional metal–carboxylate layers pillared by an alloxazine-derived bis(pyridyl) ligand, giving rise to interpenetrated three-dimensional frameworks with accessible channels of ca. 8 × 11 Å2. The compounds present a high thermal stability (>320 °C) and a very low SA, when exposed to gas adsorption. Electrochemical studies on 1-Zn and 2-Zn demonstrate reversible ligand-centred redox activity, and for 2-Zn the additional reduction of the azo-derivative ligand could be observed. To the best of our knowledge, this work reports the first pillared Coordination compound incorporating two redox-active ligands.",
  "abstract_shown": true,
  "affiliations": [],
  "article_type": null,
  "arxiv": null,
  "author_total": 5,
  "authors": [
    {
      "name": "Jaison Casas"
    },
    {
      "name": "Nathalie Kyritsakas"
    },
    {
      "name": "Corinne Bailly"
    },
    {
      "name": "Abdelaziz Jouaiti"
    },
    {
      "name": "Sylvie Ferlay"
    }
  ],
  "bibtex": "https://research.draconitic.com/paper/8mk956at3e10h.bib",
  "cited_by": 0,
  "doi": "10.1039/d6ce00622a",
  "fulltext_url": null,
  "id": "8mk956at3e10h",
  "issns": [
    "1466-8033"
  ],
  "landing_url": "https://hal.science/hal-05801617v1",
  "language": "en",
  "licence": "CC-BY-NC-ND-4.0",
  "licence_label": "CC BY-NC-ND 4.0",
  "licence_source": "article",
  "licence_url": "https://creativecommons.org/licenses/by-nc-nd/4.0/",
  "metadata_licence": null,
  "native_subjects": [
    [
      "hal",
      "0.chim"
    ],
    [
      "hal",
      "1.chim.coor"
    ],
    [
      "hal",
      "1.chim.poly"
    ],
    [
      "openalex",
      "1604|Metal-Organic Frameworks: Synthesis and Applications"
    ]
  ],
  "openalex": "W7207698232",
  "pdf_url": "https://hal.science/hal-05801617/document",
  "pmcid": null,
  "pmid": null,
  "published": "2026-10-15",
  "publisher": "Royal Society of Chemistry",
  "ris": "https://research.draconitic.com/paper/8mk956at3e10h.ris",
  "sources": [
    {
      "first_seen": "2026-10-30T12:17:57Z",
      "native_id": "hal-05801617",
      "source": "hal",
      "url": "https://hal.science/hal-05801617v1"
    }
  ],
  "subjects": [
    {
      "field": "chemistry",
      "origin": "hal:1.chim.coor",
      "subfield": "inorganic"
    },
    {
      "field": "chemistry",
      "origin": "hal:1.chim.poly",
      "subfield": "materials-polymers"
    }
  ],
  "title": "Redox-active alloxazine-based pillared coordination polymers featuring azo/alkene dicarboxylate linkers",
  "title_text": "Redox-active alloxazine-based pillared coordination polymers featuring azo/alkene dicarboxylate linkers",
  "type": "peer-reviewed",
  "updated_at": "2026-10-30T12:17:57Z",
  "url": "https://research.draconitic.com/paper/8mk956at3e10h",
  "venue": "CrystEngComm",
  "versions": []
}