{
  "abstract": "We report the synthesis of a series of thio-iminoquinoline and thio-iminotetrahydroacridine SNN ligands for application in Fe-catalyzed hydrosilylation of olefins. In the hydrosilylation of styrene, the iminoquinoline ligands provide higher yields than the iminotetrahydroacridine derivatives. However, the acridine-based Fe catalysts have longer catalyst lifetimes and at low catalyst loadings (0.5 mol% Fe) provide higher turnover numbers (up to 2000 TON). The SNN-iron catalysts provide good yields in the hydrosilylation of both styrenyl and terminal olefins but fail to hydrosilylate 1,1- and 1,2- disubstituted styrenes, hindered and electron rich styrenes, or internal alkenes.",
  "abstract_shown": true,
  "affiliations": [
    "Department of Chemistry and Biochemistry",
    "Brigham Young University",
    "Kingwood Research & Technology Center",
    "University of California"
  ],
  "article_type": null,
  "arxiv": null,
  "author_total": 12,
  "authors": [
    {
      "affs": [
        0,
        1
      ],
      "name": "Jeffrey N. Evenson"
    },
    {
      "affs": [
        0,
        1
      ],
      "name": "Nathanael A. Taylor"
    },
    {
      "affs": [
        0,
        1
      ],
      "name": "Travis A. Ferrin"
    },
    {
      "affs": [
        0,
        1
      ],
      "name": "Emma L. Richardson"
    },
    {
      "affs": [
        0,
        1
      ],
      "name": "Gregorio H. Villarreal-Quiroga"
    },
    {
      "affs": [
        0,
        1
      ],
      "name": "Stacey J. Smith"
    },
    {
      "affs": [
        2
      ],
      "name": "Mike S. Webster-Gardiner"
    },
    {
      "affs": [
        2
      ],
      "name": "Julie A. Leseberg"
    },
    {
      "affs": [
        2
      ],
      "name": "Brooke L. Small"
    },
    {
      "affs": [
        0,
        3
      ],
      "name": "Rashmi Semwal"
    },
    {
      "affs": [
        0,
        3
      ],
      "name": "Michael Findlater"
    },
    {
      "affs": [
        0,
        1
      ],
      "name": "David J. Michaelis"
    }
  ],
  "bibtex": "https://research.draconitic.com/paper/8z3j22h9m8qwv.bib",
  "cited_by": 0,
  "doi": "10.26434/chemrxiv.15008413/v1",
  "fulltext_url": null,
  "id": "8z3j22h9m8qwv",
  "issns": [],
  "landing_url": "https://chemrxiv.org/doi/full/10.26434/chemrxiv.15008413/v1",
  "language": null,
  "licence": "CC-BY-NC-ND",
  "licence_label": "CC BY-NC-ND",
  "licence_source": "journal",
  "licence_url": "https://creativecommons.org/licenses/by-nc-nd/4.0/",
  "metadata_licence": null,
  "native_subjects": [
    [
      "openalex",
      "1605|Organoboron and organosilicon chemistry"
    ]
  ],
  "openalex": "W7211894215",
  "pdf_url": "https://chemrxiv.org/doi/pdf/10.26434/chemrxiv.15008413/v1",
  "pmcid": null,
  "pmid": null,
  "published": "2026-09-07",
  "publisher": "American Chemical Society (ACS)",
  "ris": "https://research.draconitic.com/paper/8z3j22h9m8qwv.ris",
  "sources": [
    {
      "first_seen": "2026-10-30T12:17:17Z",
      "native_id": "10.26434/chemrxiv.15008413",
      "source": "chemrxiv",
      "url": "https://chemrxiv.org/doi/full/10.26434/chemrxiv.15008413/v1"
    }
  ],
  "subjects": [
    {
      "field": "chemistry",
      "origin": "openalex:1605|Organoboron and organosilicon chemistry",
      "subfield": "organic"
    }
  ],
  "title": "Synthesis of Quinoline- and Tetrahydroacridine-based SNN Ligands for Fe-catalyzed Olefin Hydrosilylation",
  "title_text": "Synthesis of Quinoline- and Tetrahydroacridine-based SNN Ligands for Fe-catalyzed Olefin Hydrosilylation",
  "type": "preprint",
  "updated_at": "2026-10-30T12:17:17Z",
  "url": "https://research.draconitic.com/paper/8z3j22h9m8qwv",
  "venue": "ChemRxiv",
  "versions": []
}