{
  "abstract": "The preparation of novel chiral λ 3 ‐iodane reagents bearing transferable halogen‐, oxygen‐ or carbon‐based ligands is described. Among these hypervalent iodine(III)‐based compounds are (i) the first chiral bis(cyano‐λ 3 ‐iodane), whose bis(benziodazolone) structure is derived from an enantiopure cyclohexyldiamine‐based bis(amidoiodoarene), and (ii) the two first chiral benziodoxolones bearing a carbon‐based ligand (i.e., cyano and trifluoromethyl groups) together with a lactate moiety ortho ‐positioned to the iodine(III) atom. The proposed iodine‐containing heterocyclic structures of these new λ 3 ‐iodanes are supported by x‐ray diffraction analyses and DFT calculations. Their capacity to transfer their ligand(s) in an asymmetric fashion to different substrates (i.e., β‐ketoesters, naphthols, and oxindoles) was also examined.",
  "abstract_shown": true,
  "affiliations": [
    "Univ. Bordeaux ISM (CNRS‐UMR 5255) Talence Cedex France",
    "CNRS/UNIV PAU & PAYS ADOUR IPREM (CNRS‐UMR 5254) Pau Cedex France"
  ],
  "article_type": "research article",
  "arxiv": null,
  "author_total": 5,
  "authors": [
    {
      "affs": [
        0
      ],
      "name": "Emmanuel Valzer",
      "orcid": "0009-0000-1740-6988"
    },
    {
      "affs": [
        1
      ],
      "name": "Jean‐Marc Sotiropoulos",
      "orcid": "0000-0001-9513-3639"
    },
    {
      "affs": [
        1
      ],
      "name": "Karinne Miqueu",
      "orcid": "0000-0002-5960-1877"
    },
    {
      "affs": [
        0
      ],
      "name": "Laurent Pouységu",
      "orcid": "0000-0002-4310-848X"
    },
    {
      "affs": [
        0
      ],
      "name": "Stéphane Quideau",
      "orcid": "0000-0002-7079-9757"
    }
  ],
  "bibtex": "https://research.draconitic.com/paper/9ewa0awstby4q.bib",
  "cited_by": 0,
  "doi": "10.1002/chem.71441",
  "fulltext_url": "https://pmc.ncbi.nlm.nih.gov/articles/PMC13730012/",
  "id": "9ewa0awstby4q",
  "issns": [
    "0947-6539",
    "1521-3765"
  ],
  "landing_url": "https://univ-pau.hal.science/hal-05778292v1",
  "language": "en",
  "licence": "CC-BY-NC-ND-4.0",
  "licence_label": "CC BY-NC-ND 4.0",
  "licence_source": "article",
  "licence_url": "https://creativecommons.org/licenses/by-nc-nd/4.0/",
  "metadata_licence": null,
  "native_subjects": [
    [
      "hal",
      "0.chim"
    ],
    [
      "heading",
      "Research Article"
    ],
    [
      "openalex",
      "1605|Oxidative Organic Chemistry Reactions"
    ]
  ],
  "openalex": "W7172416852",
  "pdf_url": "https://univ-pau.hal.science/hal-05778292/document",
  "pmcid": "PMC13730012",
  "pmid": "42549512",
  "published": "2026-08-04",
  "publisher": "Wiley-VCH Verlag",
  "ris": "https://research.draconitic.com/paper/9ewa0awstby4q.ris",
  "sources": [
    {
      "first_seen": "2026-10-30T12:17:50Z",
      "native_id": "hal-05778292",
      "source": "hal",
      "url": "https://univ-pau.hal.science/hal-05778292v1"
    },
    {
      "first_seen": "2026-11-07T12:22:42Z",
      "native_id": "PMC13730012",
      "source": "pmc",
      "url": "https://doi.org/10.1002/chem.71441"
    }
  ],
  "subjects": [
    {
      "field": "chemistry",
      "origin": "openalex:1605|Oxidative Organic Chemistry Reactions",
      "subfield": "organic"
    }
  ],
  "title": "Synthesis and Structures of Novel Chiral Cyclic Hypervalent Iodine(III) Reagents for Metal‐Free Ligand‐Transfer Reactions",
  "title_text": "Synthesis and Structures of Novel Chiral Cyclic Hypervalent Iodine(III) Reagents for Metal‐Free Ligand‐Transfer Reactions",
  "type": "peer-reviewed",
  "updated_at": "2026-11-07T12:22:42Z",
  "url": "https://research.draconitic.com/paper/9ewa0awstby4q",
  "venue": "Chemistry - A European Journal",
  "versions": []
}