{
  "abstract": "The molecular complex [V(=O)(Mes)₃] (1) reacts with silica partially dehydroxylated at 700°C (SiO₂-700) to afford [(≡SiO)V(=O)(Mes)₂] (2) as major surface species, while a bis-grafted surface species [(≡SiO)₂V(=O)(Mes)] (3) is obtained on SiO₂₋₂₀₀. These surface species were characterized by DRIFT, RAMAN, ¹H, ¹³C and ⁵¹V solid state NMR and XAFS spectroscopies and show an activity in non-oxidative dehydrogenation of propane at 500 °C. The bipodal surface organometallic complex displays a higher selectivity in propylene compared to the monopodal species.",
  "abstract_shown": true,
  "affiliations": [],
  "article_type": null,
  "arxiv": null,
  "author_total": 11,
  "authors": [
    {
      "name": "Kai Szeto"
    },
    {
      "name": "Björn Loges"
    },
    {
      "name": "Nicolas Merle"
    },
    {
      "name": "Nicolas Popoff"
    },
    {
      "name": "Alessandra Quadrelli"
    },
    {
      "name": "Hongpeng Jia"
    },
    {
      "name": "Elise Berrier"
    },
    {
      "name": "Aimery de Mallmann"
    },
    {
      "name": "Laurent Delevoye"
    },
    {
      "name": "Régis M. Gauvin"
    },
    {
      "name": "Mostafa Taoufik"
    }
  ],
  "bibtex": "https://research.draconitic.com/paper/9f3a98cxxfw65.bib",
  "cited_by": 52,
  "doi": "10.1021/om400795s",
  "fulltext_url": null,
  "id": "9f3a98cxxfw65",
  "issns": [
    "0276-7333",
    "1520-6041"
  ],
  "landing_url": "https://hal.science/hal-05772975v1",
  "language": "en",
  "licence": "CC-BY-NC-ND-4.0",
  "licence_label": "CC BY-NC-ND 4.0",
  "licence_source": "article",
  "licence_url": "https://creativecommons.org/licenses/by-nc-nd/4.0/",
  "metadata_licence": null,
  "native_subjects": [
    [
      "hal",
      "0.chim"
    ],
    [
      "hal",
      "1.chim.cata"
    ],
    [
      "hal",
      "1.chim.orga"
    ],
    [
      "openalex",
      "1503|Catalysis and Oxidation Reactions"
    ]
  ],
  "openalex": "W2324266404",
  "pdf_url": "https://hal.science/hal-05772975/document",
  "pmcid": null,
  "pmid": null,
  "published": "2026-10-01",
  "publisher": "American Chemical Society",
  "ris": "https://research.draconitic.com/paper/9f3a98cxxfw65.ris",
  "sources": [
    {
      "first_seen": "2026-10-30T12:17:45Z",
      "native_id": "hal-05772975",
      "source": "hal",
      "url": "https://hal.science/hal-05772975v1"
    }
  ],
  "subjects": [
    {
      "field": "chemistry",
      "origin": "hal:1.chim.cata",
      "subfield": "catalysis"
    },
    {
      "field": "chemistry",
      "origin": "hal:1.chim.orga",
      "subfield": "organic"
    }
  ],
  "title": "Vanadium Oxo Organometallic Species Supported on Silica for the Selective Non-oxidative Dehydrogenation of Propane",
  "title_text": "Vanadium Oxo Organometallic Species Supported on Silica for the Selective Non-oxidative Dehydrogenation of Propane",
  "type": "peer-reviewed",
  "updated_at": "2026-10-30T12:17:45Z",
  "url": "https://research.draconitic.com/paper/9f3a98cxxfw65",
  "venue": "Organometallics",
  "versions": []
}