{
  "abstract": "Fluoride-activated silicon catalysis enables radical benzylic C(sp3)–H amination of cyclic benzylic ethers and amines with bench-stable chloramine-T under transition-metal-free conditions. Mechanistic studies support a previously unexplored fluoride-promoted silicon catalytic cycle involving N-silyl sulfonamide intermediates, radical-mediated hydrogen-atom transfer, oxocarbenium ion formation for N,O-aminals, and iminium ion formation for N,N-aminals, providing an efficient platform for direct benzylic C–N bond formation.",
  "abstract_shown": true,
  "affiliations": [
    "Department of Energy Science, Sungkyunkwa University Suwon 16419 Republic of Korea +82-31-299-6505 +82-31-299-4276",
    "Department of Energy, Sungkyunkwan University Suwon 16419 Republic of Korea"
  ],
  "article_type": "research article",
  "arxiv": null,
  "author_total": 5,
  "authors": [
    {
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      "name": "Geun Ho Kim",
      "orcid": "0009-0009-8813-7469"
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    {
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      "name": "Huimyoung Byeon"
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    {
      "affs": [
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      "name": "Dong Wan Kim"
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    {
      "affs": [
        0
      ],
      "name": "Dae Won Kim"
    },
    {
      "affs": [
        0,
        1
      ],
      "name": "Jung Woon Yang",
      "orcid": "0000-0001-8636-0901"
    }
  ],
  "bibtex": "https://research.draconitic.com/paper/9hr66r7kj3a2h.bib",
  "cited_by": 0,
  "doi": "10.1039/d6sc06229f",
  "fulltext_url": "https://pmc.ncbi.nlm.nih.gov/articles/PMC13613150/",
  "id": "9hr66r7kj3a2h",
  "issns": [
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    "2041-6539"
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  "landing_url": "https://doi.org/10.1039/d6sc06229f",
  "language": "en",
  "licence": "CC-BY-NC-3.0",
  "licence_label": "CC BY-NC 3.0",
  "licence_source": "article",
  "licence_url": "https://creativecommons.org/licenses/by-nc/3.0/",
  "metadata_licence": null,
  "native_subjects": [
    [
      "heading",
      "Chemistry"
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    [
      "openalex",
      "1605|Radical Photochemical Reactions"
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  "openalex": "W7213541854",
  "pdf_url": null,
  "pmcid": "PMC13613150",
  "pmid": "42798898",
  "published": "2026-09-18",
  "publisher": "Royal Society of Chemistry",
  "ris": "https://research.draconitic.com/paper/9hr66r7kj3a2h.ris",
  "sources": [
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      "first_seen": "2026-10-31T12:23:46Z",
      "native_id": "PMC13613150",
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      "url": "https://doi.org/10.1039/d6sc06229f"
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  "subjects": [
    {
      "field": "chemistry",
      "origin": "openalex:1605|Radical Photochemical Reactions",
      "subfield": "organic"
    }
  ],
  "title": "Fluoride-activated silicon catalysis enables C(sp3)–H amination of cyclic benzylic ethers and amines using chloramine-T",
  "title_text": "Fluoride-activated silicon catalysis enables C(sp3)–H amination of cyclic benzylic ethers and amines using chloramine-T",
  "type": "peer-reviewed",
  "updated_at": "2026-11-01T12:20:54Z",
  "url": "https://research.draconitic.com/paper/9hr66r7kj3a2h",
  "venue": "Chemical Science",
  "versions": []
}