{
  "abstract": "Systematically modulating the structural environment of solid-state materials is critical for tailoring physical-chemical interactions. Here, we demonstrated the synthesis and characteristics of three hybrid zincophosphite frameworks (NTOU-12a, -12b, and -12c) that were designed by using Hard-Soft (HSAB) principles to modulate lanthanide adsorption and luminescence. In the replacement of oxygen-donor dicarboxylate ligands with a sulfur-containing linker (2,5-thiophenedicarboxylic acid), the local coordination environment and structural chemistry were systematically modified while preserving the overall framework architecture. This substitution led to 27-42% and 32-41% decreases in uptake of Eu3+ and Tb3+ ions, respectively. By tuning the ratio of adsorbed Eu3+/Tb3+ on the title compounds, the emission color could be continuously tuned over a wide spectral range. Notably, NTOU-12a exhibited white-light emission under 254 nm excitation. These results demonstrate that rational ligand substitution provides an effective strategy for designing crystalline materials with selective lanthanide adsorption and tunable multicolor luminescence.",
  "abstract_shown": true,
  "affiliations": [
    "Department of Bioscience and Biotechnology, National Taiwan Ocean University, Keelung202301, Taiwan, R.O.C.",
    "Department of Microelectronics Engineering, National Kaohsiung University of Science and Technology, Kaohsiung811213, Taiwan, R.O.C.",
    "Department of Graduate Institute of Aquaculture, National Kaohsiung University of Science and Technology, Kaohsiung811213, Taiwan, R.O.C.",
    "Bioresource Collection and Research Center, Food Industry Research and Development Institute, Hsinchu300197, Taiwan, R.O.C."
  ],
  "article_type": "research article",
  "arxiv": null,
  "author_total": 9,
  "authors": [
    {
      "affs": [
        0
      ],
      "name": "Mu-Chien Yin"
    },
    {
      "affs": [
        1
      ],
      "name": "Chih-Feng Yen"
    },
    {
      "affs": [
        2
      ],
      "name": "Tzu-Yuan Sung"
    },
    {
      "affs": [
        0
      ],
      "name": "Ju-Ying Chen"
    },
    {
      "affs": [
        0
      ],
      "name": "Jui Hsieh"
    },
    {
      "affs": [
        0
      ],
      "name": "Chun-Ru Hsu"
    },
    {
      "affs": [
        0
      ],
      "name": "Wei-Cheng Chen"
    },
    {
      "affs": [
        3
      ],
      "name": "Ming-Der Wu"
    },
    {
      "affs": [
        0
      ],
      "name": "Chih-Min Wang",
      "orcid": "0000-0002-0891-4523"
    }
  ],
  "bibtex": "https://research.draconitic.com/paper/axqpbz778qrm4.bib",
  "cited_by": 0,
  "doi": "10.1021/acs.inorgchem.6c04380",
  "fulltext_url": "https://europepmc.org/articles/PMC13625946",
  "id": "axqpbz778qrm4",
  "issns": [
    "0020-1669",
    "1520-510X"
  ],
  "landing_url": "https://europepmc.org/article/MED/42916469",
  "language": "eng",
  "licence": "CC-BY",
  "licence_label": "CC BY",
  "licence_source": "article",
  "licence_url": "https://creativecommons.org/licenses/by/4.0/",
  "metadata_licence": null,
  "native_subjects": [
    [
      "openalex",
      "1604|Metal-Organic Frameworks: Synthesis and Applications"
    ]
  ],
  "openalex": "W7212379749",
  "pdf_url": "https://europepmc.org/articles/PMC13625946?pdf=render",
  "pmcid": "PMC13625946",
  "pmid": "42916469",
  "published": "2026-09-01",
  "publisher": null,
  "ris": "https://research.draconitic.com/paper/axqpbz778qrm4.ris",
  "sources": [
    {
      "first_seen": "2026-10-30T12:21:02Z",
      "native_id": "MED:42916469",
      "source": "europepmc",
      "url": "https://europepmc.org/article/MED/42916469"
    }
  ],
  "subjects": [
    {
      "field": "chemistry",
      "origin": "openalex:1604|Metal-Organic Frameworks: Synthesis and Applications",
      "subfield": "inorganic"
    }
  ],
  "title": "Ligand Substitution in Three Organic-Inorganic Hybrid Zincophosphite Analogs: Modulating Lanthanide Affinity and White-Light Emission via Hard-Soft Acid-Base Interplay.",
  "title_text": "Ligand Substitution in Three Organic-Inorganic Hybrid Zincophosphite Analogs: Modulating Lanthanide Affinity and White-Light Emission via Hard-Soft Acid-Base Interplay.",
  "type": "peer-reviewed",
  "updated_at": "2026-10-30T12:21:02Z",
  "url": "https://research.draconitic.com/paper/axqpbz778qrm4",
  "venue": "Inorganic chemistry",
  "versions": []
}