{
  "abstract": "The straightforward access to simple halo(bismuth)amides bearing the core structural motif [Bi(NMe2)nX3-n] (X = Cl, Br, I; n = 1, 2) has been investigated, along with their coordination chemistry and their reactivity toward CS2. The latter revealed selective insertion reactions to give literature-known and new bismuth compounds with the dithiocarbamate (S2CNMe2)- ligand scaffold. Their behavior toward a cyclic(alkyl)(amino) carbene (CAAC) has been studied, demonstrating that redox processes are less relevant than in simple bismuth halides and halo(bismuth)amides and that the coordination of the CAAC ligand dominates instead. Exposing bismuth dithiocarbamates to reducing conditions revealed the complex anion [Bi(S2CNMe2)4]-, an unprecedented structural motif in pnictogen chemistry. The rational synthesis of [Li(py)4][Bi(S2CNMe2)4] provided synthetic access to this motif. Finally, the potential of the neutral species [Bi(S2CNMe2)3] as a single-source precursor for the temperature-induced formation of Bi2S3 has been investigated.",
  "abstract_shown": true,
  "affiliations": [
    "Department of Chemistry, Philipps-University Marburg, Hans-Meerwein-Str. 4, D-35032Marburg, Germany.",
    "mar.quest | Marburg Center for Quantum Materials and Sustainable Technologies, D-35032Marburg, Germany.",
    "Department of Chemistry, Faculty of Science, Mansoura University, Dakahlia Governorate, 11432Mansoura, Egypt.",
    "Institute of Chemistry, Carl von Ossietzky Universität Oldenburg, Ammerländer Heerstraße 114-118, D-26129Oldenburg, Germany.",
    "Materials Science Center and Department of Physics, Philipps-University Marburg, Hans-Meerwein-Str. 6, D-35032Marburg, Germany."
  ],
  "article_type": "research article",
  "arxiv": null,
  "author_total": 9,
  "authors": [
    {
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        0,
        1
      ],
      "name": "Gargi Kundu"
    },
    {
      "affs": [
        0,
        1
      ],
      "name": "Frerik Wurm"
    },
    {
      "affs": [
        0
      ],
      "name": "Kai Oberdorf"
    },
    {
      "affs": [
        0,
        1,
        2
      ],
      "name": "Ahmed Fetoh"
    },
    {
      "affs": [
        3
      ],
      "name": "Pulkit Dhankhar"
    },
    {
      "affs": [
        1,
        4
      ],
      "name": "Celina Becker"
    },
    {
      "affs": [
        3
      ],
      "name": "Johanna Heine",
      "orcid": "0000-0002-6795-5288"
    },
    {
      "affs": [
        1,
        4
      ],
      "name": "Kerstin Volz"
    },
    {
      "affs": [
        0,
        1
      ],
      "name": "Crispin Lichtenberg",
      "orcid": "0000-0002-0176-0939"
    }
  ],
  "bibtex": "https://research.draconitic.com/paper/c6npvnw0xzrsc.bib",
  "cited_by": 0,
  "doi": "10.1021/acs.inorgchem.6c03443",
  "fulltext_url": "https://europepmc.org/articles/PMC13664088",
  "id": "c6npvnw0xzrsc",
  "issns": [
    "0020-1669",
    "1520-510X"
  ],
  "landing_url": "https://europepmc.org/article/MED/42916933",
  "language": "eng",
  "licence": "CC-BY",
  "licence_label": "CC BY",
  "licence_source": "article",
  "licence_url": "https://creativecommons.org/licenses/by/4.0/",
  "metadata_licence": null,
  "native_subjects": [
    [
      "openalex",
      "1604|Synthesis and characterization of novel inorganic/organometallic compounds"
    ]
  ],
  "openalex": "W7214959507",
  "pdf_url": "https://europepmc.org/articles/PMC13664088?pdf=render",
  "pmcid": "PMC13664088",
  "pmid": "42916933",
  "published": "2026-10-01",
  "publisher": null,
  "ris": "https://research.draconitic.com/paper/c6npvnw0xzrsc.ris",
  "sources": [
    {
      "first_seen": "2026-10-30T12:20:36Z",
      "native_id": "MED:42916933",
      "source": "europepmc",
      "url": "https://europepmc.org/article/MED/42916933"
    }
  ],
  "subjects": [
    {
      "field": "chemistry",
      "origin": "openalex:1604|Synthesis and characterization of novel inorganic/organometallic compounds",
      "subfield": "inorganic"
    }
  ],
  "title": "Insertion of CS2 into Bi-N Bonds: Coordination Chemistry and Reactivity of Bismuth Dithiocarbamates.",
  "title_text": "Insertion of CS2 into Bi-N Bonds: Coordination Chemistry and Reactivity of Bismuth Dithiocarbamates.",
  "type": "peer-reviewed",
  "updated_at": "2026-10-30T12:20:36Z",
  "url": "https://research.draconitic.com/paper/c6npvnw0xzrsc",
  "venue": "Inorganic chemistry",
  "versions": []
}