{
  "abstract": "Treatment of [Mo7O24]6- with 0.05 N HNO3 at pH ∼ 1.8 in the presence of seed crystals of the ammonium salt of Mo-13 isopolymolybdate led to the formation of the title salt, which appears to represent the first reported 12- charged form of this com-position. Analysis of the Mo-O-Mo bond distances obtained from single-crystal X-ray diffraction supports the formulation of the anion in the ammonium com-pound as [Mo36O112(OH)4(H2O)10]12-. Charge balance requires 12 ammonium counter-ions, and the presence of 26 cocrystallized water mol-ecules gives the overall formula (NH4)12[Mo36O112(OH)4(H2O)10]·26H2O. This structure differs from previously reported Mo36 isopolymolybdate phases, including K8[Mo36O112(H2O)16]·36H2O, (H2bipy)4[Mo36O112(H2O)16]·28H2O, {(CH3NH3)8[Mo36O112(H2O)14]·19H2O·2.1(CH3NH3·NO3)} n , (CH3NH3)10[Mo36O112(OH)2(H2O)14]·9H2O, and K10[Mo36O110(OH)6(H2O)12]·38H2O.",
  "abstract_shown": true,
  "affiliations": [
    "GGP Nano Materials, LLC, 2611 Parmenter Blvd., Royal Oak, Michigan 48073, USA.",
    "Department of Chemistry Wayne State University, 5101 Cass Avenue Detroit Michigan 48202 USA.",
    "Lumigen Instrument Center Wayne State University, 5101 Cass Avenue Detroit Michigan 48202 USA."
  ],
  "article_type": "research article",
  "arxiv": null,
  "author_total": 3,
  "authors": [
    {
      "affs": [
        0
      ],
      "name": "Rajpal S Gaur"
    },
    {
      "affs": [
        1
      ],
      "name": "Stephanie L Brock"
    },
    {
      "affs": [
        2
      ],
      "name": "Cassandra L Ward"
    }
  ],
  "bibtex": "https://research.draconitic.com/paper/c6p2k19mt903x.bib",
  "cited_by": 0,
  "doi": "10.1107/s2056989026010388",
  "fulltext_url": "https://europepmc.org/articles/PMC13741338",
  "id": "c6p2k19mt903x",
  "issns": [
    "2056-9890"
  ],
  "landing_url": "https://europepmc.org/article/MED/42997434",
  "language": "eng",
  "licence": "CC-BY",
  "licence_label": "CC BY",
  "licence_source": "article",
  "licence_url": "https://creativecommons.org/licenses/by/4.0/",
  "metadata_licence": null,
  "native_subjects": [
    [
      "openalex",
      "2505|Polyoxometalates: Synthesis and Applications"
    ]
  ],
  "openalex": "W7221615103",
  "pdf_url": "https://europepmc.org/articles/PMC13741338?pdf=render",
  "pmcid": "PMC13741338",
  "pmid": "42997434",
  "published": "2026-10-13",
  "publisher": null,
  "ris": "https://research.draconitic.com/paper/c6p2k19mt903x.ris",
  "sources": [
    {
      "first_seen": "2026-11-09T15:20:41Z",
      "native_id": "MED:42997434",
      "source": "europepmc",
      "url": "https://europepmc.org/article/MED/42997434"
    }
  ],
  "subjects": [
    {
      "field": "chemistry",
      "origin": "openalex:2505|Polyoxometalates: Synthesis and Applications",
      "subfield": "materials-polymers"
    }
  ],
  "title": "Synthesis and structure of (NH₄)₁₂[Mo₃₆O₁₁₂(OH)₄(H₂O)₁₀], the first example of the [Mo₃₆O₁₁₂]⁸⁻ molybdate anion cluster to bear a charge of 12.",
  "title_text": "Synthesis and structure of (NH₄)₁₂[Mo₃₆O₁₁₂(OH)₄(H₂O)₁₀], the first example of the [Mo₃₆O₁₁₂]⁸⁻ molybdate anion cluster to bear a charge of 12.",
  "type": "peer-reviewed",
  "updated_at": "2026-11-09T15:20:41Z",
  "url": "https://research.draconitic.com/paper/c6p2k19mt903x",
  "venue": "Acta crystallographica. Section E, Crystallographic communications",
  "versions": []
}