{
  "abstract": "A dinuclear silver(I) com-plex of 6-phenyl-2,2':6',2''-terpyridine, bis-(μ-6-phenyl-2,2':6',2''-terpyridine)-bis-[(tri-fluoro-methane-sulfonato)-silver(I)], [Ag2(C21H15N3)(CF3SO3)2], was obtained by crystallization with silver tri-fluoro-methane-sulfonate and characterized by single-crystal X-ray diffraction. Two symmetry-related terpyridine ligands bridge two AgI ions. The AgI ion has a highly distorted four-coordinate N3O environment com-prising three pyridyl N atoms and one tri-fluoro-methane-sulfonate O atom. The intra-molecular Ag⋯Ag separation of 2.8501 (8) Å is consistent with an argentophilic inter-action. An intra-molecular phen-yl-pyridyl π-π contact is also present. The structure demonstrates that a single phenyl substituent at the 6-position is com-patible with ligand bridging and the formation of a short Ag⋯Ag contact.",
  "abstract_shown": true,
  "affiliations": [
    "Department of Applied and Materials Chemistry College of Science and Technology Nihon University, 1-8-14 Kanda Surugadai Chiyoda-ku Tokyo 101-8308 Japan."
  ],
  "article_type": "research article",
  "arxiv": null,
  "author_total": 5,
  "authors": [
    {
      "affs": [
        0
      ],
      "name": "Yuto Nakaie"
    },
    {
      "affs": [
        0
      ],
      "name": "Tomoya Abe"
    },
    {
      "affs": [
        0
      ],
      "name": "Yosuke Hosoya",
      "orcid": "0009-0008-7299-7424"
    },
    {
      "affs": [
        0
      ],
      "name": "Kosuke Sugawa",
      "orcid": "0000-0002-3434-4632"
    },
    {
      "affs": [
        0
      ],
      "name": "Joe Otsuki",
      "orcid": "0000-0001-9974-6037"
    }
  ],
  "bibtex": "https://research.draconitic.com/paper/c8r968ax8phdb.bib",
  "cited_by": 0,
  "doi": "10.1107/s2414314626010436",
  "fulltext_url": "https://europepmc.org/articles/PMC13741258",
  "id": "c8r968ax8phdb",
  "issns": [
    "2414-3146"
  ],
  "landing_url": "https://europepmc.org/article/MED/42997380",
  "language": "eng",
  "licence": "CC-BY",
  "licence_label": "CC BY",
  "licence_source": "article",
  "licence_url": "https://creativecommons.org/licenses/by/4.0/",
  "metadata_licence": null,
  "native_subjects": [
    [
      "openalex",
      "1604|Crystal structures of chemical compounds"
    ]
  ],
  "openalex": "W7222120776",
  "pdf_url": "https://europepmc.org/articles/PMC13741258?pdf=render",
  "pmcid": "PMC13741258",
  "pmid": "42997380",
  "published": "2026-09-01",
  "publisher": null,
  "ris": "https://research.draconitic.com/paper/c8r968ax8phdb.ris",
  "sources": [
    {
      "first_seen": "2026-11-09T15:20:42Z",
      "native_id": "MED:42997380",
      "source": "europepmc",
      "url": "https://europepmc.org/article/MED/42997380"
    }
  ],
  "subjects": [
    {
      "field": "chemistry",
      "origin": "openalex:1604|Crystal structures of chemical compounds",
      "subfield": "inorganic"
    }
  ],
  "title": "A dinuclear silver(I) com-plex of 6-phenyl-2,2':6',2''-terpyridine.",
  "title_text": "A dinuclear silver(I) com-plex of 6-phenyl-2,2':6',2''-terpyridine.",
  "type": "peer-reviewed",
  "updated_at": "2026-11-09T15:20:42Z",
  "url": "https://research.draconitic.com/paper/c8r968ax8phdb",
  "venue": "IUCrData",
  "versions": []
}