{
  "abstract": "The crystal structure of the mixed-valent compound PbTe3O8(= PbIITeIV2TeVIO8), lead(II) bis-[oxidotellurate(IV)] tellurate(VI), is isotypic with that of SrTe3O8. It comprises 1∞[Te3O8]2- chains sharing O atoms to form a framework with two types of square channels extending parallel to [001]. The smaller channels (diameter ∼4 Å) are occupied by 12-coordinate PbII atoms in the centre of the channel, whereas the slightly larger channels (diameter ∼4.5 Å) accommodate the stereoactive 5s2 electron lone pair of TeIV.",
  "abstract_shown": true,
  "affiliations": [
    "Institute for Chemical Technologies and Analytics, Division of Applied Solid State Chemistry, TU Wien, Getreidemarkt 9/E164-05-1, A-1060, Vienna, Austria."
  ],
  "article_type": "research article",
  "arxiv": null,
  "author_total": 1,
  "authors": [
    {
      "affs": [
        0
      ],
      "name": "Matthias Weil",
      "orcid": "0000-0001-5235-9910"
    }
  ],
  "bibtex": "https://research.draconitic.com/paper/cn9gyjw5rk172.bib",
  "cited_by": 0,
  "doi": "10.1107/s2056989026010996",
  "fulltext_url": "https://europepmc.org/articles/PMC13741337",
  "id": "cn9gyjw5rk172",
  "issns": [
    "2056-9890"
  ],
  "landing_url": "https://europepmc.org/article/MED/42997426",
  "language": "eng",
  "licence": "CC-BY",
  "licence_label": "CC BY",
  "licence_source": "article",
  "licence_url": "https://creativecommons.org/licenses/by/4.0/",
  "metadata_licence": null,
  "native_subjects": [
    [
      "openalex",
      "2504|Crystal Structures and Properties"
    ]
  ],
  "openalex": "W7224865939",
  "pdf_url": "https://europepmc.org/articles/PMC13741337?pdf=render",
  "pmcid": "PMC13741337",
  "pmid": "42997426",
  "published": "2026-10-30",
  "publisher": null,
  "ris": "https://research.draconitic.com/paper/cn9gyjw5rk172.ris",
  "sources": [
    {
      "first_seen": "2026-11-09T15:20:34Z",
      "native_id": "MED:42997426",
      "source": "europepmc",
      "url": "https://europepmc.org/article/MED/42997426"
    }
  ],
  "subjects": [
    {
      "field": "chemistry",
      "origin": "openalex:2504|Crystal Structures and Properties",
      "subfield": "materials-polymers"
    }
  ],
  "title": "Synthesis and crystal structure of the mixed-valent TeIV/VI compound PbTe₃O₈.",
  "title_text": "Synthesis and crystal structure of the mixed-valent TeIV/VI compound PbTe₃O₈.",
  "type": "peer-reviewed",
  "updated_at": "2026-11-09T15:20:34Z",
  "url": "https://research.draconitic.com/paper/cn9gyjw5rk172",
  "venue": "Acta crystallographica. Section E, Crystallographic communications",
  "versions": []
}