{
  "abstract": "Pulsed EPR hyperfine spectroscopy of the formal rare earth(ii) arene complexes [REII(NHAriPr6)2] (2M, M = Sc, Y, La; NHAriPr6 = {N(H)C6H3-2,6-(C6H2-2,4,6-iPr3)2}), supported by DFT, reveals extensive delocalisation of spin density to the arene ring bound to the metal (56–73% Mulliken spin population, 42–53% Löwdin orbital population of SOMO, from DFT). Hence, they are RE(ii) complexes in a formal sense only.",
  "abstract_shown": true,
  "affiliations": [
    "Photon Science Institute, Centre for Radiochemical Research and Department of Chemistry, The University of Manchester Manchester M13 9PL UK"
  ],
  "article_type": "brief report",
  "arxiv": null,
  "author_total": 5,
  "authors": [
    {
      "affs": [
        0
      ],
      "name": "Tomáš Hajdu"
    },
    {
      "affs": [
        0
      ],
      "name": "Ross E. MacKenzie"
    },
    {
      "affs": [
        0
      ],
      "name": "Floriana Tuna",
      "orcid": "0000-0002-5541-1750"
    },
    {
      "affs": [
        0
      ],
      "name": "Conrad A. P. Goodwin",
      "orcid": "0000-0002-4320-2548"
    },
    {
      "affs": [
        0
      ],
      "name": "Eric J. L. McInnes",
      "orcid": "0000-0002-4090-7040"
    }
  ],
  "bibtex": "https://research.draconitic.com/paper/cp7p9b3hncw7r.bib",
  "cited_by": 0,
  "doi": "10.1039/d6cc06362d",
  "fulltext_url": "https://pmc.ncbi.nlm.nih.gov/articles/PMC13711156/",
  "id": "cp7p9b3hncw7r",
  "issns": [
    "1359-7345",
    "1364-548X"
  ],
  "landing_url": "https://doi.org/10.1039/d6cc06362d",
  "language": "en",
  "licence": "CC-BY-3.0",
  "licence_label": "CC BY 3.0",
  "licence_source": "article",
  "licence_url": "https://creativecommons.org/licenses/by/3.0/",
  "metadata_licence": null,
  "native_subjects": [
    [
      "heading",
      "Chemistry"
    ],
    [
      "openalex",
      "2504|Magnetism in coordination complexes"
    ]
  ],
  "openalex": "W7223176955",
  "pdf_url": "https://pubs.rsc.org/cc/article-pdf/doi/10.1039/D6CC06362D/14936297/d6cc06362d.pdf",
  "pmcid": "PMC13711156",
  "pmid": "42935463",
  "published": "2026-10-22",
  "publisher": null,
  "ris": "https://research.draconitic.com/paper/cp7p9b3hncw7r.ris",
  "sources": [
    {
      "first_seen": "2026-10-31T12:21:59Z",
      "native_id": "PMC13711156",
      "source": "pmc",
      "url": "https://doi.org/10.1039/d6cc06362d"
    }
  ],
  "subjects": [
    {
      "field": "chemistry",
      "origin": "openalex:2504|Magnetism in coordination complexes",
      "subfield": "materials-polymers"
    }
  ],
  "title": "Pulsed hyperfine EPR study of formally divalent rare earth (scandium, yttrium, lanthanum) arene complexes",
  "title_text": "Pulsed hyperfine EPR study of formally divalent rare earth (scandium, yttrium, lanthanum) arene complexes",
  "type": "peer-reviewed",
  "updated_at": "2026-10-31T12:21:59Z",
  "url": "https://research.draconitic.com/paper/cp7p9b3hncw7r",
  "venue": "Chemical Communications (Cambridge, England)",
  "versions": []
}