{
  "abstract": "Bis(germaamides) and their thio- and seleno- analogs are unknown. This work reports the isolation and characterization of the first examples of thio- and seleno-analogs of bis(germaamides) 7 and 8 containing two Ge(E)NR2 moieties (E = S, Se; R = SiMe3). These compounds were obtained by oxidizing the bulky pyrrole-imine dimeric ligand-stabilized bis(aminogermylene) 5 with elemental sulfur and selenium. This study also highlights the first-ever application of the bulky pyrrole-imine dimeric ligand 3 to simultaneously stabilize two low-valent centers (germylenes or stannylenes). Furthermore, the bonding in the thio- and seleno-bis(germaamides) 7 and 8 was investigated in detail using single–crystal X-ray diffraction and DFT calculations.",
  "abstract_shown": true,
  "affiliations": [
    "Department of Chemistry",
    "Indian Institute of Technology Delhi"
  ],
  "article_type": null,
  "arxiv": null,
  "author_total": 6,
  "authors": [
    {
      "affs": [
        0,
        1
      ],
      "name": "Tanya Batra"
    },
    {
      "affs": [
        0,
        1
      ],
      "name": "Prakash Chandra Joshi"
    },
    {
      "affs": [
        0,
        1
      ],
      "name": "Vishal Singh"
    },
    {
      "affs": [
        0,
        1
      ],
      "name": "Hemant Kumar"
    },
    {
      "affs": [
        0,
        1
      ],
      "name": "Subrata Kundu"
    },
    {
      "affs": [
        0,
        1
      ],
      "name": "Selvarajan Nagendran",
      "orcid": "0000-0003-1053-8878"
    }
  ],
  "bibtex": "https://research.draconitic.com/paper/cw1r28vap2dct.bib",
  "cited_by": 0,
  "doi": "10.26434/chemrxiv.15009138/v1",
  "fulltext_url": null,
  "id": "cw1r28vap2dct",
  "issns": [],
  "landing_url": "https://chemrxiv.org/doi/full/10.26434/chemrxiv.15009138/v1",
  "language": null,
  "licence": "CC-BY-NC-ND",
  "licence_label": "CC BY-NC-ND",
  "licence_source": "journal",
  "licence_url": "https://creativecommons.org/licenses/by-nc-nd/4.0/",
  "metadata_licence": null,
  "native_subjects": [
    [
      "openalex",
      "1604|Synthesis and characterization of novel inorganic/organometallic compounds"
    ]
  ],
  "openalex": "W7213925403",
  "pdf_url": "https://chemrxiv.org/doi/pdf/10.26434/chemrxiv.15009138/v1",
  "pmcid": null,
  "pmid": null,
  "published": "2026-09-21",
  "publisher": "American Chemical Society (ACS)",
  "ris": "https://research.draconitic.com/paper/cw1r28vap2dct.ris",
  "sources": [
    {
      "first_seen": "2026-10-30T12:17:19Z",
      "native_id": "10.26434/chemrxiv.15009138",
      "source": "chemrxiv",
      "url": "https://chemrxiv.org/doi/full/10.26434/chemrxiv.15009138/v1"
    }
  ],
  "subjects": [
    {
      "field": "chemistry",
      "origin": "openalex:1604|Synthesis and characterization of novel inorganic/organometallic compounds",
      "subfield": "inorganic"
    }
  ],
  "title": "Pyrrole-Imine Dimer Stabilized Bis(germaamides) with two Ge(E)N(SiMe3)2 moieties (E = S, Se)",
  "title_text": "Pyrrole-Imine Dimer Stabilized Bis(germaamides) with two Ge(E)N(SiMe3)2 moieties (E = S, Se)",
  "type": "preprint",
  "updated_at": "2026-10-30T12:17:19Z",
  "url": "https://research.draconitic.com/paper/cw1r28vap2dct",
  "venue": "ChemRxiv",
  "versions": []
}