{
  "abstract": "We have thoroughly explored the conversion of alkenyl and epoxy carbamates into cyclic carbonate alcohols. The substrate scope is robust, and the products are amenable to further transformations. In almost all cases, the reactions are predictably regioselective and stereospecific. The reactions can be run open to air and without precautions to exclude moisture. Indeed, H2O plays a critical role in the transformations and is added to the reactions as a key reagent.",
  "abstract_shown": true,
  "affiliations": [
    "Department of Medicinal Chemistry",
    "University of Kansas",
    "Department of Chemistry",
    "University of Missouri—Columbia"
  ],
  "article_type": null,
  "arxiv": null,
  "author_total": 4,
  "authors": [
    {
      "affs": [
        0,
        1
      ],
      "name": "Raju Silver"
    },
    {
      "affs": [
        0,
        1
      ],
      "name": "Dnyaneshwar A. Gorve"
    },
    {
      "affs": [
        2,
        3
      ],
      "name": "Steven P. Kelley"
    },
    {
      "affs": [
        0,
        1
      ],
      "name": "Shyam Sathyamoorthi",
      "orcid": "0000-0003-4705-7349"
    }
  ],
  "bibtex": "https://research.draconitic.com/paper/d3k5p6n2nd2jc.bib",
  "cited_by": 0,
  "doi": "10.26434/chemrxiv.15010491/v1",
  "fulltext_url": null,
  "id": "d3k5p6n2nd2jc",
  "issns": [],
  "landing_url": "https://chemrxiv.org/doi/full/10.26434/chemrxiv.15010491/v1",
  "language": null,
  "licence": "CC-BY-NC-ND",
  "licence_label": "CC BY-NC-ND",
  "licence_source": "journal",
  "licence_url": "https://creativecommons.org/licenses/by-nc-nd/4.0/",
  "metadata_licence": null,
  "native_subjects": [
    [
      "openalex",
      "1508|Carbon dioxide utilization in catalysis"
    ]
  ],
  "openalex": "W7222212068",
  "pdf_url": "https://chemrxiv.org/doi/pdf/10.26434/chemrxiv.15010491/v1",
  "pmcid": null,
  "pmid": null,
  "published": "2026-10-15",
  "publisher": "American Chemical Society (ACS)",
  "ris": "https://research.draconitic.com/paper/d3k5p6n2nd2jc.ris",
  "sources": [
    {
      "first_seen": "2026-10-30T12:17:24Z",
      "native_id": "10.26434/chemrxiv.15010491",
      "source": "chemrxiv",
      "url": "https://chemrxiv.org/doi/full/10.26434/chemrxiv.15010491/v1"
    }
  ],
  "subjects": [
    {
      "field": "chemistry",
      "origin": "source:chemrxiv",
      "subfield": "general"
    }
  ],
  "title": "Stereospecific Conversion of Alkenyl and Epoxy Carbamates into Cyclic Carbonate Alcohols",
  "title_text": "Stereospecific Conversion of Alkenyl and Epoxy Carbamates into Cyclic Carbonate Alcohols",
  "type": "preprint",
  "updated_at": "2026-10-30T12:17:24Z",
  "url": "https://research.draconitic.com/paper/d3k5p6n2nd2jc",
  "venue": "ChemRxiv",
  "versions": []
}