{
  "abstract": "The use of 1-{[dimethyl(phenylthiomethyl)silyl]methyl}piperidine piperidine as chelating ligand has been probed by complexation on CuI and CuBr in MeCN solution to afford the dinuclear S , N -chelate title complexes, [Cu 2 I 2 (C 15 H 25 NSSi) 2 ] and [Cu 2 Br 2 (C 15 H 25 NSSi) 2 ], which feature a halide-bridged rhomboid-shaped Cu(μ 2 - X )Cu ( X = I, Br) core with Cu...Cu contacts of 2.8249 (5) and 2.7631 (6) Å, respectively. The two isostructural complexes crystalize in the triclinic space group P 1 with half molecule in the asymmetric unit. An analysis of the Hirshfeld surfaces shows that H...H (van der Waals) interactions dominate with a contact percentage of over 80% in both complexes.",
  "abstract_shown": true,
  "affiliations": [],
  "article_type": null,
  "arxiv": null,
  "author_total": 3,
  "authors": [
    {
      "name": "Kai Schäper"
    },
    {
      "name": "Michael Knorr"
    },
    {
      "name": "Carsten Strohmann"
    }
  ],
  "bibtex": "https://research.draconitic.com/paper/d42m5186c7ajr.bib",
  "cited_by": 0,
  "doi": "10.1107/s2056989026009862",
  "fulltext_url": null,
  "id": "d42m5186c7ajr",
  "issns": [
    "2056-9890"
  ],
  "landing_url": "https://hal.science/hal-05780328v1",
  "language": "en",
  "licence": "CC-BY-4.0",
  "licence_label": "CC BY 4.0",
  "licence_source": "article",
  "licence_url": "https://creativecommons.org/licenses/by/4.0/",
  "metadata_licence": null,
  "native_subjects": [
    [
      "hal",
      "0.chim"
    ],
    [
      "openalex",
      "1604|Crystal structures of chemical compounds"
    ]
  ],
  "openalex": "W7218931535",
  "pdf_url": "https://hal.science/hal-05780328/document",
  "pmcid": null,
  "pmid": null,
  "published": "2026-10-02",
  "publisher": "International Union of Crystallography",
  "ris": "https://research.draconitic.com/paper/d42m5186c7ajr.ris",
  "sources": [
    {
      "first_seen": "2026-10-30T12:17:48Z",
      "native_id": "hal-05780328",
      "source": "hal",
      "url": "https://hal.science/hal-05780328v1"
    }
  ],
  "subjects": [
    {
      "field": "chemistry",
      "origin": "openalex:1604|Crystal structures of chemical compounds",
      "subfield": "inorganic"
    }
  ],
  "title": "Crystal structure and Hirshfeld analysis of di-μ-bromido-bis[(1-{[dimethyl(phenylthiomethyl)silyl]methyl}piperidine-κ 2 N , S )copper(I)] and di-μ-iodido-bis[(1-{[dimethyl(phenylthiomethyl)silyl]methyl}piperidine-κ 2 N , S )copper(I)]",
  "title_text": "Crystal structure and Hirshfeld analysis of di-μ-bromido-bis[(1-{[dimethyl(phenylthiomethyl)silyl]methyl}piperidine-κ 2 N , S )copper(I)] and di-μ-iodido-bis[(1-{[dimethyl(phenylthiomethyl)silyl]methyl}piperidine-κ 2 N , S )copper(I)]",
  "type": "peer-reviewed",
  "updated_at": "2026-10-30T12:17:48Z",
  "url": "https://research.draconitic.com/paper/d42m5186c7ajr",
  "venue": "Acta crystallographica Section E : Crystallographic communications [2015-...]",
  "versions": []
}