{
  "abstract": "The combination of cellulose-based materials and functional polymers is a promising approach for the preparation of porous, biotemplated ceramic materials. Within this study, cellulose substrates were functionalized with a surface-attached initiator followed by polymerization of (3‑methacryloxypropyl)heptaisobutyl-T8-silsesquioxane (MAPOSS) by means of surface-initiated atom transfer radical polymerization (ATRP). Successful functionalization was proven by infrared (IR) spectroscopy as well as by contact angle (CA) measurements. Thermal analysis of the polymer-modified cellulose substrates in different atmospheres (nitrogen and air) up to 600 °C led to porous carbon materials featuring the pristine fibre-like structure of the cellulose material as shown by scanning electron microscopy (SEM). Interestingly, spherical, silicon-containing domains were present at the surface of the cellulose-templated carbon fibres after further ceramisation at 1600 °C, as investigated by energy dispersive X-ray spectroscopy (EDS) and X-ray diffraction (XRD) measurements.",
  "abstract_shown": true,
  "affiliations": [],
  "article_type": null,
  "arxiv": null,
  "author_total": 6,
  "authors": [
    {
      "name": "Christian Rüttiger"
    },
    {
      "name": "Steffen Vowinkel"
    },
    {
      "name": "Nicole Herzog"
    },
    {
      "name": "Kathrin Hofmann"
    },
    {
      "name": "Emanuel Ionescu"
    },
    {
      "name": "Markus Gallei"
    }
  ],
  "bibtex": "https://research.draconitic.com/paper/d4p01zm6mcmgf.bib",
  "cited_by": 1,
  "doi": "10.3390/coatings8120446",
  "fulltext_url": null,
  "id": "d4p01zm6mcmgf",
  "issns": [
    "2079-6412"
  ],
  "landing_url": "https://hal.science/hal-05789798v1",
  "language": "en",
  "licence": "CC-BY",
  "licence_label": "CC BY",
  "licence_source": "journal",
  "licence_url": "https://creativecommons.org/licenses/by/4.0/",
  "metadata_licence": null,
  "native_subjects": [
    [
      "hal",
      "0.chim"
    ],
    [
      "openalex",
      "2505|Silicone and Siloxane Chemistry"
    ]
  ],
  "openalex": "W2902060313",
  "pdf_url": "https://www.mdpi.com/2079-6412/8/12/446/pdf?version=1545029905",
  "pmcid": null,
  "pmid": null,
  "published": "2026-10-09",
  "publisher": "MDPI",
  "ris": "https://research.draconitic.com/paper/d4p01zm6mcmgf.ris",
  "sources": [
    {
      "first_seen": "2026-10-30T12:17:52Z",
      "native_id": "hal-05789798",
      "source": "hal",
      "url": "https://hal.science/hal-05789798v1"
    }
  ],
  "subjects": [
    {
      "field": "chemistry",
      "origin": "openalex:2505|Silicone and Siloxane Chemistry",
      "subfield": "materials-polymers"
    }
  ],
  "title": "POSS-containing polymethacrylates on cellulose-based substrates: Immobilization and ceramic formation",
  "title_text": "POSS-containing polymethacrylates on cellulose-based substrates: Immobilization and ceramic formation",
  "type": "peer-reviewed",
  "updated_at": "2026-10-30T12:17:52Z",
  "url": "https://research.draconitic.com/paper/d4p01zm6mcmgf",
  "venue": "Coatings",
  "versions": []
}