{
  "abstract": "The activation of chalcogenoglycosides for O-glycosylation often requires strong electrophiles and a low temperature. However, visible-light irradiation of electron donor-acceptor (EDA) complexes between chalcogenoglycosides and less reactive electrophiles can circumvent this problem. Herein, we demonstrate high-yielding, room-temperature O-glycosylation with selenoglycosides in the presence of diphenyliodonium salts. Experimental and computational evidence indicates the formation of halogen-bonded EDA complexes and photoinduced electron transfer as critical steps.",
  "abstract_shown": true,
  "affiliations": [
    "Department of Chemistry, Louisiana State University, Baton Rouge, Louisiana70803, United States.",
    "Département de Chimie Moléculaire, Université Grenoble Alpes, UMR CNRS 5250, 38000Grenoble, France."
  ],
  "article_type": "research article",
  "arxiv": null,
  "author_total": 7,
  "authors": [
    {
      "affs": [
        0
      ],
      "name": "Vinayak Pradeep"
    },
    {
      "affs": [
        0
      ],
      "name": "Afsana Mimi"
    },
    {
      "affs": [
        1
      ],
      "name": "Marina Descoubes"
    },
    {
      "affs": [
        0
      ],
      "name": "Erik Alvarez Valenzuela"
    },
    {
      "affs": [
        0
      ],
      "name": "Semin Lee",
      "orcid": "0000-0003-0873-9507"
    },
    {
      "affs": [
        1
      ],
      "name": "Anne Milet",
      "orcid": "0000-0002-1480-4451"
    },
    {
      "affs": [
        0
      ],
      "name": "Justin R Ragains",
      "orcid": "0000-0002-2521-5396"
    }
  ],
  "bibtex": "https://research.draconitic.com/paper/d5kqeav2s23t0.bib",
  "cited_by": 0,
  "doi": "10.1021/acs.orglett.6c03759",
  "fulltext_url": "https://europepmc.org/articles/PMC13640423",
  "id": "d5kqeav2s23t0",
  "issns": [
    "1523-7060",
    "1523-7052"
  ],
  "landing_url": "https://hal.science/hal-05768600v1",
  "language": "en",
  "licence": "CC-BY",
  "licence_label": "CC BY",
  "licence_source": "article",
  "licence_url": "https://creativecommons.org/licenses/by/4.0/",
  "metadata_licence": null,
  "native_subjects": [
    [
      "hal",
      "0.chim"
    ],
    [
      "openalex",
      "1605|Carbohydrate Chemistry and Synthesis"
    ]
  ],
  "openalex": "W7214010673",
  "pdf_url": "https://europepmc.org/articles/PMC13640423?pdf=render",
  "pmcid": "PMC13640423",
  "pmid": "42917825",
  "published": "2026-09-22",
  "publisher": "American Chemical Society",
  "ris": "https://research.draconitic.com/paper/d5kqeav2s23t0.ris",
  "sources": [
    {
      "first_seen": "2026-10-30T12:17:42Z",
      "native_id": "hal-05768600",
      "source": "hal",
      "url": "https://hal.science/hal-05768600v1"
    },
    {
      "first_seen": "2026-10-30T12:20:36Z",
      "native_id": "MED:42917825",
      "source": "europepmc",
      "url": "https://europepmc.org/article/MED/42917825"
    }
  ],
  "subjects": [
    {
      "field": "chemistry",
      "origin": "openalex:1605|Carbohydrate Chemistry and Synthesis",
      "subfield": "organic"
    }
  ],
  "title": "Visible-Light-Promoted O-Glycosylation Mediated by Halogen Bonding of Selenoglycosides to the Diphenyliodonium Ion",
  "title_text": "Visible-Light-Promoted O-Glycosylation Mediated by Halogen Bonding of Selenoglycosides to the Diphenyliodonium Ion",
  "type": "peer-reviewed",
  "updated_at": "2026-10-30T12:20:36Z",
  "url": "https://research.draconitic.com/paper/d5kqeav2s23t0",
  "venue": "Organic Letters",
  "versions": []
}