{
  "abstract": "New thermoplastic nonisocyanate poly(hydroxyurethanes) (NIPUs) have been designed by polyaddition reactions of carvyl acetate dicarbonate (CADC) with a range of commercial diamines, yielding thermoplastic nonisocyanate poly(hydroxyurethanes) with moderate molecular weights and glass transition temperatures (Tg) ranging from -30.5 to 62 °C. Thermal curing of the Jeffamine-derived poly(hydroxyurethane) with the polyacrylate compound LAROMER LR 9000 resulted in the formation of sticky thermoset materials, showing potential for adhesive applications. In addition, curing of bis(glydycyl ether dicarbonate) (BGDC)/CADC blends with polyethylene imine (PEI) enables the formation of tailor-made NIPU thermosets with high stiffness, tensile strength, and low elongation at break.",
  "abstract_shown": true,
  "affiliations": [
    "Universidad de Castilla-La Mancha , Departamento de Química Inorgánica, Orgánica y Bioquímica-Centro de Innovación en Química Avanzada (ORFEO-CINQA), Facultad de Ciencias y Tecnologías Químicas and Instituto Regional de Investigación Científica Aplicada-IRICA, 13071Ciudad Real, Spain.",
    "Departamento de Química Inorgánica, Orgánica y Bioquímica-Centro de Innovación en Química Avanzada (ORFEO-CINQA), Facultad de Farmacia, Universidad de Castilla-La Mancha, 02071Albacete, Spain.",
    "Departamento de Química Inorgánica, Facultad de Ciencias, Universidad de Granada, 18071Granada, Spain.",
    "TA Instruments Waters Chromatography, Tres Cantos, 28760Madrid, Spain."
  ],
  "article_type": "research article",
  "arxiv": null,
  "author_total": 11,
  "authors": [
    {
      "affs": [
        0
      ],
      "name": "Marc Martínez de Sarasa Buchaca"
    },
    {
      "affs": [
        0
      ],
      "name": "Jesús Naranjo",
      "orcid": "0000-0003-3961-5013"
    },
    {
      "affs": [
        0
      ],
      "name": "Alberto Moreno-Fernández"
    },
    {
      "affs": [
        1
      ],
      "name": "Carmen Moya-López"
    },
    {
      "affs": [
        2
      ],
      "name": "Pablo Salcedo-Abraira",
      "orcid": "0000-0003-4812-8938"
    },
    {
      "affs": [
        2
      ],
      "name": "Antonio Rodríguez-Diéguez",
      "orcid": "0000-0003-3198-5378"
    },
    {
      "affs": [
        3
      ],
      "name": "Carlos Gracia-Fernández"
    },
    {
      "affs": [
        0
      ],
      "name": "Antonio M Rodríguez-García",
      "orcid": "0000-0002-4405-2406"
    },
    {
      "affs": [
        0
      ],
      "name": "José A Castro-Osma",
      "orcid": "0000-0002-5029-0507"
    },
    {
      "affs": [
        0
      ],
      "name": "Felipe de la Cruz-Martínez",
      "orcid": "0000-0003-3720-9345"
    },
    {
      "affs": [
        0
      ],
      "name": "Agustín Lara-Sánchez",
      "orcid": "0000-0001-6547-4862"
    }
  ],
  "bibtex": "https://research.draconitic.com/paper/d8p616z2bh37b.bib",
  "cited_by": 0,
  "doi": "10.1021/acs.biomac.6c01553",
  "fulltext_url": "https://europepmc.org/articles/PMC13690295",
  "id": "d8p616z2bh37b",
  "issns": [
    "1525-7797",
    "1526-4602"
  ],
  "landing_url": "https://europepmc.org/article/MED/42912581",
  "language": "eng",
  "licence": "CC-BY",
  "licence_label": "CC BY",
  "licence_source": "article",
  "licence_url": "https://creativecommons.org/licenses/by/4.0/",
  "metadata_licence": null,
  "native_subjects": [
    [
      "openalex",
      "2507|Polymer composites and self-healing"
    ]
  ],
  "openalex": "W7202069259",
  "pdf_url": "https://europepmc.org/articles/PMC13690295?pdf=render",
  "pmcid": "PMC13690295",
  "pmid": "42912581",
  "published": "2026-10-01",
  "publisher": null,
  "ris": "https://research.draconitic.com/paper/d8p616z2bh37b.ris",
  "sources": [
    {
      "first_seen": "2026-10-30T12:20:14Z",
      "native_id": "MED:42912581",
      "source": "europepmc",
      "url": "https://europepmc.org/article/MED/42912581"
    }
  ],
  "subjects": [
    {
      "field": "chemistry",
      "origin": "openalex:2507|Polymer composites and self-healing",
      "subfield": "materials-polymers"
    }
  ],
  "title": "Terpene-Derived Carvyl Acetate Dicarbonate: A Novel Monomer for Biobased Nonisocyanate Poly(hydroxyurethane) Thermoplastics and Thermosets.",
  "title_text": "Terpene-Derived Carvyl Acetate Dicarbonate: A Novel Monomer for Biobased Nonisocyanate Poly(hydroxyurethane) Thermoplastics and Thermosets.",
  "type": "peer-reviewed",
  "updated_at": "2026-10-30T12:20:14Z",
  "url": "https://research.draconitic.com/paper/d8p616z2bh37b",
  "venue": "Biomacromolecules",
  "versions": []
}