{
  "abstract": "Peroxycarbonate (CO4 2–) is implicated in various biological, catalytic, and energy storage processes – despite the capability of transition metals to guide the reactivity of this unstable intermediate toward productive ends, the coordination chemistry of metal–peroxycarbonate complexes, M(CO4), remains poorly understood. Herein, we describe the synthesis, isolation, and structural characterization of two platinum(II) peroxycarbonate complexes Pt(PPh3)2(CO4) (1) and Pt(dppe)(CO4) (2) (dppe = 1,2‐bis(diphenylphosphino)ethane). Whereas the complexes are thermally stable, they react by oxygen‐atom transfer (OAT) when irradiated with visible light. This photoreactivity was investigated using NMR and FT‐IR photolysis to identify structures of reaction intermediates and photoproducts, together with kinetic analyses, which establish unimolecular OAT from the CO4 2− ligand to the bound phosphine. In addition to providing rare examples of structurally characterized M(CO4) complexes, this work is the first demonstration of photochemical reactivity in a peroxycarbonate complex.",
  "abstract_shown": true,
  "affiliations": [
    "Department of Chemistry and Chemical Biology Harvard University Cambridge Massachusetts USA",
    "Present address: Department of Chemistry Northwestern University Evanston Illinois USA"
  ],
  "article_type": "research article",
  "arxiv": null,
  "author_total": 5,
  "authors": [
    {
      "affs": [
        0
      ],
      "name": "Meghan G. Sullivan",
      "orcid": "0000-0002-0862-3072"
    },
    {
      "affs": [
        0,
        1
      ],
      "name": "Jesse B. Gordon",
      "orcid": "0000-0002-6331-7940"
    },
    {
      "affs": [
        0
      ],
      "name": "Brandon M. Campbell",
      "orcid": "0000-0002-9359-9862"
    },
    {
      "affs": [
        0
      ],
      "name": "Shao‐Liang Zheng",
      "orcid": "0000-0002-6432-9943"
    },
    {
      "affs": [
        0
      ],
      "name": "Daniel G. Nocera",
      "orcid": "0000-0001-5055-320X"
    }
  ],
  "bibtex": "https://research.draconitic.com/paper/dcj14pj9p0k54.bib",
  "cited_by": 0,
  "doi": "10.1002/anie.5181266",
  "fulltext_url": "https://pmc.ncbi.nlm.nih.gov/articles/PMC13725566/",
  "id": "dcj14pj9p0k54",
  "issns": [
    "1433-7851",
    "1521-3773"
  ],
  "landing_url": "https://doi.org/10.1002/anie.5181266",
  "language": "en",
  "licence": "CC-BY-4.0",
  "licence_label": "CC BY 4.0",
  "licence_source": "article",
  "licence_url": "https://creativecommons.org/licenses/by/4.0/",
  "metadata_licence": null,
  "native_subjects": [
    [
      "heading",
      "COMMUNICATION"
    ],
    [
      "heading",
      "Communication"
    ],
    [
      "heading",
      "Hot Paper"
    ],
    [
      "openalex",
      "1605|Organometallic Complex Synthesis and Catalysis"
    ]
  ],
  "openalex": "W7214151230",
  "pdf_url": "https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/anie.5181266",
  "pmcid": "PMC13725566",
  "pmid": "42781925",
  "published": "2026-09-24",
  "publisher": null,
  "ris": "https://research.draconitic.com/paper/dcj14pj9p0k54.ris",
  "sources": [
    {
      "first_seen": "2026-11-04T12:23:55Z",
      "native_id": "PMC13725566",
      "source": "pmc",
      "url": "https://doi.org/10.1002/anie.5181266"
    }
  ],
  "subjects": [
    {
      "field": "chemistry",
      "origin": "openalex:1605|Organometallic Complex Synthesis and Catalysis",
      "subfield": "organic"
    }
  ],
  "title": "Photochemical Oxygen‐Atom‐Transfer Reactivity of Platinum(II) Peroxycarbonates",
  "title_text": "Photochemical Oxygen‐Atom‐Transfer Reactivity of Platinum(II) Peroxycarbonates",
  "type": "peer-reviewed",
  "updated_at": "2026-11-06T12:21:46Z",
  "url": "https://research.draconitic.com/paper/dcj14pj9p0k54",
  "venue": "Angewandte Chemie (International Ed. in English)",
  "versions": []
}