{
  "abstract": "Herein, we report the reactivity of a monocoordinate bismuthinidene (1) with various organic azides. The reaction of 1 with p‐toluenesulfonyl azide resulted in the formation of an unprecedented, unsupported iminobismuthane (2), which features the shortest reported Bi–N distance of 2.041(3) Å in an iminobismuthane. Conversely, the reaction of 1 with 4‐azidobiphenyl resulted in the first example of a species containing a tetraazabismole (BiN4) heterocycle (3). We also highlight that 1 demonstrates catalytic activity, enabling the reduction of a selection of organic azides.",
  "abstract_shown": true,
  "affiliations": [
    "Max‐Planck‐Institut für Kohlenforschung Mülheim an der Ruhr Germany",
    "Max‐Planck‐Institute For Chemical Energy Conversion Mülheim an der Ruhr Germany",
    "Rigaku Europe SE Neu‐Isenburg Germany"
  ],
  "article_type": "research article",
  "arxiv": null,
  "author_total": 10,
  "authors": [
    {
      "affs": [
        0
      ],
      "name": "Marcel Potocnik"
    },
    {
      "affs": [
        0
      ],
      "name": "Kristian L. Mears",
      "orcid": "0000-0002-8515-4177"
    },
    {
      "affs": [
        0
      ],
      "name": "Davide Spinnato"
    },
    {
      "affs": [
        1
      ],
      "name": "Gabriele Deplano",
      "orcid": "0000-0002-0505-7722"
    },
    {
      "affs": [
        0
      ],
      "name": "Nils Nöthling",
      "orcid": "0000-0001-9709-8187"
    },
    {
      "affs": [
        0
      ],
      "name": "Markus Leutzsch",
      "orcid": "0000-0001-8171-9399"
    },
    {
      "affs": [
        0
      ],
      "name": "Maurice van Gastel"
    },
    {
      "affs": [
        2
      ],
      "name": "Khai‐Nghi Truong",
      "orcid": "0000-0001-9764-7350"
    },
    {
      "affs": [
        1
      ],
      "name": "Serena DeBeer",
      "orcid": "0000-0002-5196-3400"
    },
    {
      "affs": [
        0
      ],
      "name": "Josep Cornella",
      "orcid": "0000-0003-4152-7098"
    }
  ],
  "bibtex": "https://research.draconitic.com/paper/df8p987m7htts.bib",
  "cited_by": 0,
  "doi": "10.1002/anie.2998568",
  "fulltext_url": "https://pmc.ncbi.nlm.nih.gov/articles/PMC13725612/",
  "id": "df8p987m7htts",
  "issns": [
    "1433-7851",
    "1521-3773"
  ],
  "landing_url": "https://doi.org/10.1002/anie.2998568",
  "language": "en",
  "licence": "CC-BY-4.0",
  "licence_label": "CC BY 4.0",
  "licence_source": "article",
  "licence_url": "https://creativecommons.org/licenses/by/4.0/",
  "metadata_licence": null,
  "native_subjects": [
    [
      "heading",
      "Research Article"
    ],
    [
      "openalex",
      "1604|Synthesis and characterization of novel inorganic/organometallic compounds"
    ]
  ],
  "openalex": "W7213535056",
  "pdf_url": "https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/anie.2998568",
  "pmcid": "PMC13725612",
  "pmid": "42758020",
  "published": "2026-09-18",
  "publisher": null,
  "ris": "https://research.draconitic.com/paper/df8p987m7htts.ris",
  "sources": [
    {
      "first_seen": "2026-11-04T12:23:57Z",
      "native_id": "PMC13725612",
      "source": "pmc",
      "url": "https://doi.org/10.1002/anie.2998568"
    }
  ],
  "subjects": [
    {
      "field": "chemistry",
      "origin": "openalex:1604|Synthesis and characterization of novel inorganic/organometallic compounds",
      "subfield": "inorganic"
    }
  ],
  "title": "Access to Unsupported Iminobismuthane and Tetraazabismole Species Enabled by a Rigid and Bulky Organobismuthinidene",
  "title_text": "Access to Unsupported Iminobismuthane and Tetraazabismole Species Enabled by a Rigid and Bulky Organobismuthinidene",
  "type": "peer-reviewed",
  "updated_at": "2026-11-04T12:23:57Z",
  "url": "https://research.draconitic.com/paper/df8p987m7htts",
  "venue": "Angewandte Chemie (International Ed. in English)",
  "versions": []
}