{
  "abstract": "The conversion of nitrobenzene to aniline can be carried out under ultramild conditions (35 °C under N2 at ambient pressure) with a 40% molar excess of hydrazine as reducing agent mediated by metal-organic alloy NiGraf in aqueous tetrahydrofuran, a green solvent. Conversion of nitrobenzene to aniline will optimally employ the stable and recyclable form of the NiGraf, consisting of reduced graphene oxide entrapped in jamborite nanoparticles, in renewable solvent system H2O/THF.",
  "abstract_shown": true,
  "affiliations": [
    "Dipartimento di Chimica",
    "Università degli Studi di Milano",
    "Istituto per lo Studio dei Materiali Nanostrutturati, CNR",
    "Department of Inorganic Chemistry, Crystallography, and Mineralogy",
    "University of Malaga",
    "Università degli Studi di Torino"
  ],
  "article_type": null,
  "arxiv": null,
  "author_total": 6,
  "authors": [
    {
      "affs": [
        0,
        1
      ],
      "name": "Mario Orgnoni",
      "orcid": "0009-0002-8061-1882"
    },
    {
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      "name": "Rosaria Ciriminna",
      "orcid": "0000-0001-6596-1572"
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    {
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        4
      ],
      "name": "Enrique Rodríguez-Castellón",
      "orcid": "0000-0003-4751-1767"
    },
    {
      "affs": [
        0,
        5
      ],
      "name": "Giuseppina Cerrato",
      "orcid": "0000-0001-8536-1398"
    },
    {
      "affs": [
        2
      ],
      "name": "Mario Pagliaro",
      "orcid": "0000-0002-5096-329X"
    },
    {
      "affs": [
        0,
        1
      ],
      "name": "Cristina Della Pina",
      "orcid": "0000-0001-5628-0337"
    }
  ],
  "bibtex": "https://research.draconitic.com/paper/dgbqxrfyr2446.bib",
  "cited_by": 0,
  "doi": "10.26434/chemrxiv.15009748/v1",
  "fulltext_url": null,
  "id": "dgbqxrfyr2446",
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  "landing_url": "https://chemrxiv.org/doi/full/10.26434/chemrxiv.15009748/v1",
  "language": null,
  "licence": "CC-BY-NC",
  "licence_label": "CC BY-NC",
  "licence_source": "journal",
  "licence_url": "https://creativecommons.org/licenses/by-nc/4.0/",
  "metadata_licence": null,
  "native_subjects": [
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      "openalex",
      "1605|Nanomaterials for catalytic reactions"
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  "openalex": "W7215093459",
  "pdf_url": null,
  "pmcid": null,
  "pmid": null,
  "published": "2026-10-01",
  "publisher": "American Chemical Society (ACS)",
  "ris": "https://research.draconitic.com/paper/dgbqxrfyr2446.ris",
  "sources": [
    {
      "first_seen": "2026-10-30T12:17:21Z",
      "native_id": "10.26434/chemrxiv.15009748",
      "source": "chemrxiv",
      "url": "https://chemrxiv.org/doi/full/10.26434/chemrxiv.15009748/v1"
    }
  ],
  "subjects": [
    {
      "field": "chemistry",
      "origin": "openalex:1605|Nanomaterials for catalytic reactions",
      "subfield": "organic"
    }
  ],
  "title": "Ultramild conversion of nitrobenzene to aniline mediated by metal organic alloy NiGraf in green solvent",
  "title_text": "Ultramild conversion of nitrobenzene to aniline mediated by metal organic alloy NiGraf in green solvent",
  "type": "preprint",
  "updated_at": "2026-10-30T12:17:21Z",
  "url": "https://research.draconitic.com/paper/dgbqxrfyr2446",
  "venue": "ChemRxiv",
  "versions": []
}