{
  "abstract": "Terpyridine-containing polysiloxanes (tpy-PMHS and tpy-PDMS) were synthesized via hydrosilylation and used as macromolecular ligands for coordination with copper(I) and copper(II) precursors. As a result, a series of novel polymer–metal complexes (Cu-tpy-PMHS and Cu-tpy-PDMS) with diverse architectures (cross-linked and end-functionalized polymers) and different copper oxidation states were obtained. These polymer–metal complexes were comprehensively characterized by solid-state NMR, UV–vis, X-ray photoelectron spectroscopy and thermogravimetric analysis. The redox activity of the cross-linked Cu-tpy-PMHS-2 sample was investigated using cyclic voltammetry. Cu-tpy-PDMS-1 exhibited catalytic activity in mechanochemical azide–alkyne cycloaddition, affording the target product in 80% yield.",
  "abstract_shown": true,
  "affiliations": [
    "Institute of Chemistry, St. Petersburg State University, 7/9 Universitetskaya Emb., St. Petersburg 199034, Russia"
  ],
  "article_type": null,
  "arxiv": null,
  "author_total": 5,
  "authors": [
    {
      "affs": [
        0
      ],
      "name": "Sofia S. Kryukova",
      "orcid": "0009-0001-4012-7933"
    },
    {
      "affs": [
        0
      ],
      "name": "Elena R. Votchel"
    },
    {
      "affs": [
        0
      ],
      "name": "Sergey V. Baykov"
    },
    {
      "affs": [
        0
      ],
      "name": "Vadim P. Boyarskiy",
      "orcid": "0000-0002-6038-0872"
    },
    {
      "affs": [
        0
      ],
      "name": "Regina M. Islamova",
      "orcid": "0000-0003-1180-6539"
    }
  ],
  "bibtex": "https://research.draconitic.com/paper/e0jfgkak4yrdq.bib",
  "cited_by": 0,
  "doi": "10.3390/polym18202506",
  "fulltext_url": null,
  "id": "e0jfgkak4yrdq",
  "issns": [
    "2073-4360"
  ],
  "landing_url": "https://www.mdpi.com/2073-4360/18/20/2506",
  "language": null,
  "licence": "CC-BY-4.0",
  "licence_label": "CC BY 4.0",
  "licence_source": "article",
  "licence_url": "https://creativecommons.org/licenses/by/4.0/",
  "metadata_licence": null,
  "native_subjects": [
    [
      "openalex",
      "2505|Silicone and Siloxane Chemistry"
    ]
  ],
  "openalex": "W7221594760",
  "pdf_url": null,
  "pmcid": null,
  "pmid": null,
  "published": "2026-10-13",
  "publisher": "MDPI AG",
  "ris": "https://research.draconitic.com/paper/e0jfgkak4yrdq.ris",
  "sources": [
    {
      "first_seen": "2026-10-30T12:18:44Z",
      "native_id": "10.3390/polym18202506",
      "source": "crossref",
      "url": "https://www.mdpi.com/2073-4360/18/20/2506"
    }
  ],
  "subjects": [
    {
      "field": "chemistry",
      "origin": "openalex:2505|Silicone and Siloxane Chemistry",
      "subfield": "materials-polymers"
    }
  ],
  "title": "Some Synthetic Approaches for Copper-Containing Terpyridine-Functionalized Polysiloxane Complexes",
  "title_text": "Some Synthetic Approaches for Copper-Containing Terpyridine-Functionalized Polysiloxane Complexes",
  "type": "peer-reviewed",
  "updated_at": "2026-10-30T12:18:44Z",
  "url": "https://research.draconitic.com/paper/e0jfgkak4yrdq",
  "venue": "Polymers",
  "versions": []
}