{
  "abstract": "Mono‐, bis‐, and tris(pentafluoroethyl)plumbanes of the type Pb(C2F5) n Ar4‐\n\nn (Ar = Ph, Tol, Ani; n = 1–3) are easily accessible by treatment of the corresponding arylchloroplumbanes with LiC2F5. The subsequent treatment with HCl furnishes chloro(pentafluoroethyl)plumbanes. The synthesis of the tris(pentafluoroethyl)plumbate(II) anion is facilitated by treatment of Pb(C2F5)3Cl with PPh3. In addition, formation of Pb(C2F5)4 is achieved starting from Pb(OAc)4 and is fully characterized by multinuclear NMR spectroscopy and by single crystal x‐ray diffraction of the 1,10‐phenanthroline adduct.",
  "abstract_shown": true,
  "affiliations": [
    "Fakultät für Chemie Centrum für Molekulare Materialien Universität Bielefeld Bielefeld Germany"
  ],
  "article_type": "research article",
  "arxiv": null,
  "author_total": 5,
  "authors": [
    {
      "affs": [
        0
      ],
      "name": "Michael Grasse"
    },
    {
      "affs": [
        0
      ],
      "name": "Lukas Hartmann"
    },
    {
      "affs": [
        0
      ],
      "name": "Beate Neumann"
    },
    {
      "affs": [
        0
      ],
      "name": "Hans‐Georg Stammler"
    },
    {
      "affs": [
        0
      ],
      "name": "Berthold Hoge",
      "orcid": "0000-0001-9610-8478"
    }
  ],
  "bibtex": "https://research.draconitic.com/paper/ebckvdfbct968.bib",
  "cited_by": 0,
  "doi": "10.1002/chem.71402",
  "fulltext_url": "https://pmc.ncbi.nlm.nih.gov/articles/PMC13715457/",
  "id": "ebckvdfbct968",
  "issns": [
    "0947-6539",
    "1521-3765"
  ],
  "landing_url": "https://doi.org/10.1002/chem.71402",
  "language": "en",
  "licence": "CC-BY-4.0",
  "licence_label": "CC BY 4.0",
  "licence_source": "article",
  "licence_url": "https://creativecommons.org/licenses/by/4.0/",
  "metadata_licence": null,
  "native_subjects": [
    [
      "heading",
      "Research Article"
    ],
    [
      "openalex",
      "1604|Synthesis and characterization of novel inorganic/organometallic compounds"
    ]
  ],
  "openalex": "W7169654147",
  "pdf_url": null,
  "pmcid": "PMC13715457",
  "pmid": "42470620",
  "published": "2026-07-18",
  "publisher": null,
  "ris": "https://research.draconitic.com/paper/ebckvdfbct968.ris",
  "sources": [
    {
      "first_seen": "2026-11-01T12:22:45Z",
      "native_id": "PMC13715457",
      "source": "pmc",
      "url": "https://doi.org/10.1002/chem.71402"
    }
  ],
  "subjects": [
    {
      "field": "chemistry",
      "origin": "openalex:1604|Synthesis and characterization of novel inorganic/organometallic compounds",
      "subfield": "inorganic"
    }
  ],
  "title": "Syntheses and Properties of Pentafluoroethylplumbanes in the Oxidation States +II, +III, and +IV",
  "title_text": "Syntheses and Properties of Pentafluoroethylplumbanes in the Oxidation States +II, +III, and +IV",
  "type": "peer-reviewed",
  "updated_at": "2026-11-01T12:22:45Z",
  "url": "https://research.draconitic.com/paper/ebckvdfbct968",
  "venue": "Chemistry (Weinheim an Der Bergstrasse, Germany)",
  "versions": []
}