{
  "abstract": "Herein is examined the reactivity of acetoxy-peroxyacetals as a new source of acyclic peroxycarbenium species. Their reactivity was explored with Sc(OTf)3, a mild Lewis acid that promotes peroxycarbenium species. The resilience of tert-butyldimethylsilyl group on peroxyl function was found superior for substitution reactions, enabling the additions of neutral nucleophiles such as enoxysilanes, silylcyanides, silylazides and allylsilanes. Formal [3+2] cycloaddition proceeds specifically with allyltrimethylsilane, depending on several parameters. Peroxysilanes were ultimately transformed into 1,2-dioxolanes or 1,2-dioxanes in a few steps, thanks to the promotion of a second peroxycarbenium ion, which constitutes a new approach to the synthesis of endoperoxides.",
  "abstract_shown": true,
  "affiliations": [],
  "article_type": null,
  "arxiv": null,
  "author_total": 2,
  "authors": [
    {
      "name": "Yunxin Xing"
    },
    {
      "name": "Laurent Ferrié"
    }
  ],
  "bibtex": "https://research.draconitic.com/paper/ed04c6dt1x51e.bib",
  "cited_by": 3,
  "doi": "10.1021/acs.orglett.6c00780",
  "fulltext_url": null,
  "id": "ed04c6dt1x51e",
  "issns": [
    "1523-7060",
    "1523-7052"
  ],
  "landing_url": "https://hal.science/hal-05775188v1",
  "language": "en",
  "licence": "CC-BY-NC-ND-4.0",
  "licence_label": "CC BY-NC-ND 4.0",
  "licence_source": "article",
  "licence_url": "https://creativecommons.org/licenses/by-nc-nd/4.0/",
  "metadata_licence": null,
  "native_subjects": [
    [
      "hal",
      "0.chim"
    ],
    [
      "hal",
      "1.chim.orga"
    ],
    [
      "openalex",
      "1605|Cyclopropane Reaction Mechanisms"
    ]
  ],
  "openalex": "W7148441042",
  "pdf_url": "https://hal.science/hal-05775188/document",
  "pmcid": null,
  "pmid": null,
  "published": "2026-10-02",
  "publisher": "American Chemical Society",
  "ris": "https://research.draconitic.com/paper/ed04c6dt1x51e.ris",
  "sources": [
    {
      "first_seen": "2026-10-30T12:17:46Z",
      "native_id": "hal-05775188",
      "source": "hal",
      "url": "https://hal.science/hal-05775188v1"
    }
  ],
  "subjects": [
    {
      "field": "chemistry",
      "origin": "hal:1.chim.orga",
      "subfield": "organic"
    }
  ],
  "title": "Acetoxy-Peroxyacetals: A Peroxycarbenium Precursor for the Synthesis of Hydroperoxides and Endoperoxides",
  "title_text": "Acetoxy-Peroxyacetals: A Peroxycarbenium Precursor for the Synthesis of Hydroperoxides and Endoperoxides",
  "type": "peer-reviewed",
  "updated_at": "2026-10-30T12:17:46Z",
  "url": "https://research.draconitic.com/paper/ed04c6dt1x51e",
  "venue": "Organic Letters",
  "versions": []
}