{
  "abstract": "A catalyst- and fluoride-free electrochemical method for the use of readily available thioethers as alkyl donors in C-O and C-N bond formation to furnish ethers, esters, and N-alkylated products is reported. The protocol exhibits broad functional group tolerance and is compatible with structurally complex substrates. Cyclic voltammetry studies rationalize the distinct behaviour of oxygen and nitrogen nucleophiles and guide the optimization of the electrochemical conditions, enabling the formation of coupled products from starting materials with both matched and mismatched redox potentials.",
  "abstract_shown": true,
  "affiliations": [
    "Department of Chemistry",
    "KTH Royal Institute of Technology",
    "Department of Physical and Chemical Sciences, Università degli Studi dell’Aquila, Via Vetoio, Coppito, Italy, 67100"
  ],
  "article_type": null,
  "arxiv": null,
  "author_total": 8,
  "authors": [
    {
      "affs": [
        0,
        1
      ],
      "name": "Malin Lill"
    },
    {
      "affs": [
        2
      ],
      "name": "Caterina Momoli"
    },
    {
      "affs": [
        2
      ],
      "name": "Valerio Morlacci"
    },
    {
      "affs": [
        0,
        1
      ],
      "name": "Linn Andersson"
    },
    {
      "affs": [
        2
      ],
      "name": "Willy Giaccio"
    },
    {
      "affs": [
        0,
        1
      ],
      "name": "Helena Lundberg"
    },
    {
      "affs": [
        2
      ],
      "name": "Laura Palombi"
    },
    {
      "name": "laura palombi",
      "orcid": "0000-0002-6613-7363"
    }
  ],
  "bibtex": "https://research.draconitic.com/paper/ed1j72dv5wxhq.bib",
  "cited_by": 0,
  "doi": "10.26434/chemrxiv.15010581/v1",
  "fulltext_url": null,
  "id": "ed1j72dv5wxhq",
  "issns": [],
  "landing_url": "https://chemrxiv.org/doi/full/10.26434/chemrxiv.15010581/v1",
  "language": null,
  "licence": "CC-BY",
  "licence_label": "CC BY",
  "licence_source": "journal",
  "licence_url": "https://creativecommons.org/licenses/by/4.0/",
  "metadata_licence": null,
  "native_subjects": [
    [
      "openalex",
      "1605|Radical Photochemical Reactions"
    ]
  ],
  "openalex": "W7222398008",
  "pdf_url": "https://chemrxiv.org/doi/pdf/10.26434/chemrxiv.15010581/v1",
  "pmcid": null,
  "pmid": null,
  "published": "2026-10-16",
  "publisher": "American Chemical Society (ACS)",
  "ris": "https://research.draconitic.com/paper/ed1j72dv5wxhq.ris",
  "sources": [
    {
      "first_seen": "2026-10-30T12:17:24Z",
      "native_id": "10.26434/chemrxiv.15010581",
      "source": "chemrxiv",
      "url": "https://chemrxiv.org/doi/full/10.26434/chemrxiv.15010581/v1"
    }
  ],
  "subjects": [
    {
      "field": "chemistry",
      "origin": "openalex:1605|Radical Photochemical Reactions",
      "subfield": "organic"
    }
  ],
  "title": "Thioethers as alkyl donors in electrochemical C–O and C–N bond forming reactions",
  "title_text": "Thioethers as alkyl donors in electrochemical C–O and C–N bond forming reactions",
  "type": "preprint",
  "updated_at": "2026-10-30T12:17:24Z",
  "url": "https://research.draconitic.com/paper/ed1j72dv5wxhq",
  "venue": "ChemRxiv",
  "versions": []
}