{
  "abstract": "A new two-step synthesis produces moisture-stable antimony and arsenic dithiothreitol cages. Structural analysis reveals that the Sb compounds self-assemble into reversed bilayers, consistent with pnictogen-bonded vesicle formation in organic media. The Sb assemblies more efficiently encapsulate and protect rhodamine B than the arsenic analogue or a topological mimic that lacks pnictogen-bonding capability. This work provides a synthetically accessible tool for partitioning organic media to allow for orthogonal reactivity.",
  "abstract_shown": true,
  "affiliations": [],
  "article_type": null,
  "arxiv": null,
  "author_total": 6,
  "authors": [
    {
      "name": "Lina M. Delgado"
    },
    {
      "name": "Olivia H. Villanueva"
    },
    {
      "name": "Shiva Moaven"
    },
    {
      "name": "Daniel K. Unruh"
    },
    {
      "name": "Dimitri Pappas"
    },
    {
      "name": "Anthony F. Cozzolino",
      "orcid": "0000-0002-1100-0829"
    }
  ],
  "bibtex": "https://research.draconitic.com/paper/ee483ygnsfm9c.bib",
  "cited_by": 0,
  "doi": "10.26434/chemrxiv.15005281/v2",
  "fulltext_url": null,
  "id": "ee483ygnsfm9c",
  "issns": [],
  "landing_url": "https://chemrxiv.org/doi/full/10.26434/chemrxiv.15005281/v2",
  "language": null,
  "licence": "CC-BY",
  "licence_label": "CC BY",
  "licence_source": "journal",
  "licence_url": "https://creativecommons.org/licenses/by/4.0/",
  "metadata_licence": null,
  "native_subjects": [
    [
      "openalex",
      "1605|Supramolecular Chemistry and Complexes"
    ]
  ],
  "openalex": "W7213449051",
  "pdf_url": "https://chemrxiv.org/doi/pdf/10.26434/chemrxiv.15005281/v2",
  "pmcid": null,
  "pmid": null,
  "published": "2026-09-16",
  "publisher": "American Chemical Society (ACS)",
  "ris": "https://research.draconitic.com/paper/ee483ygnsfm9c.ris",
  "sources": [
    {
      "first_seen": "2026-10-30T12:17:19Z",
      "native_id": "10.26434/chemrxiv.15005281",
      "source": "chemrxiv",
      "url": "https://chemrxiv.org/doi/full/10.26434/chemrxiv.15005281/v2"
    }
  ],
  "subjects": [
    {
      "field": "chemistry",
      "origin": "openalex:1605|Supramolecular Chemistry and Complexes",
      "subfield": "organic"
    }
  ],
  "title": "Mixed thiolate/alkoxide antimony cages for stable reversed-bilayer vesicle self-assembly",
  "title_text": "Mixed thiolate/alkoxide antimony cages for stable reversed-bilayer vesicle self-assembly",
  "type": "preprint",
  "updated_at": "2026-10-30T12:17:19Z",
  "url": "https://research.draconitic.com/paper/ee483ygnsfm9c",
  "venue": "ChemRxiv",
  "versions": []
}